A P NDICE A

FACTORES DE CONVERSldN Y VALORES DE LA CONSTANTE DE LOS GASESDebido a que los libros estndar de referencia contienen datos en diversas unidades, se incluyen las tablas A.l y A.2 para ayudar a la conversin de los valores de un conjunto de unidades a otro. Aquellas unidades que no tienen conexin con el sistema SI se encierran entre parntesis. Se notan las definiciones siguientes: (ft) E pie definido por E.U.A. E 3.048 X 10-l m (in) = pulgada definida por E.U.A. E 2.54 X lOe2 m (Ib,) = libra musa definida por E.U.A. (sistema de peso ingls) = 4.5359237 X 10-l kg (lbf) = fuerza para acelerar 1 (Ib,) por 32.1740 (ft)sm2 (atm) = presin atmosfrica estndar = 101 325 Pa (psia) = presin absoluta de libras fuerza por pulgada cuadrada (torr) = presin ejercida por 1 mm de mercurio a 0C y gravedad estndar (cal) c calora termodinmica (Btu) = unidad trmica britnica de la tabla de vapor internacional (Ib mol) = masa en libras masa con valor numrico igual a la masa molar (R) = temperatura absoluta en Rankines Los factores de conversin de la tabla A. 1 se refieren a una sola unidad bsica o derivada del sistema SI. Las conversiones entre otros pares de unidades para una magnitud dada se hacen como en el ejemplo siguiente: 1 bar = 0.986923 (atm) = 750.061 (torr) as 1 (atm) = 750.061 = 760.00 (torr) 0.986923

724

Al?NDICE

A.

Factores de conversin y valores de la constante de los gases

lbbla A.1: Magnitud Longitud Masa fierza Conversin

Factores de conversin

1 m = 100 cm = 3.28084 (ft) = 39.3701 (in) 1 kg = lo3 g = 2.20462 (Ib,) lN= 1kgmsv2 = lo5 (dina) = 0.224809 (lbf) 1 bar = = = = = = lo5 kg m-l s2 = lo5 N mT2 lo5 Pa = lo2 kPa lo6 (dina) cme 0.986923(atm) 145038(psia) 750.061(torr)

Presin

Volumen Densidad Energa

1 m3 = lo6 cm3 = 353147(ft)3, 1 g cmM = lo3 kg me3 = 62.4278(lb,)(ft)-3 1J = = = = = = = 1kgm2sm2 = 1Nm 1 m3 Pa = 10m5 m3 bar = 10 cm3 bar 9.86923 cm3 (atm) 107(dina) cm = lO(erg) 0.239006(cal) 5.12197 X 10-3(ft)3(psia) = 0,737562(ft)(lbr) 9.47831 X 10A(Btu) lo3 W = lo3 kg m2 se3 = lo3 J s-l 239.006(cal) s-l 737.562(ft)(lbf) s-l 0.947831(Btu) ss1 1.34102(hp) Valores de la constante universal de los gasas

Potencia

1 kW = = = = = lbbla A.2:

R = 8.314 J mal- K-l = 8.314 m3 Pa mal- K-

= 83.14 cm3 bar mal- K-l = 8 314 cm3 kPa mal- K-l o = 82.06 cm3 (atm) mal- K- = 62 356 cm3 (torr) mor K-l = 1.987 (cal) mal- K-l = 1.986 (Btu)(lb mal)-l(R)-l = 0.7302 (ft)3(atm)(lb mal)-l(R)- = 10.73 (ft)7 (psia)(lb mol)-(@,Y1 = 1 545 (ft)(lbf)(lb mal)-l(R)-

A P NDICE B

PROPIEDADES DE ESPECIES PURAS

Aqu se han enlistado valores para varias especies qumicas para la masa molar (peso molecular), factor acntrico o, temperatura crtica T,, presin crtica P,, factor de compresibilidad crtica Z,, volumen molar crtico V, y punto de ebullicin normal T,. Recopilados del Proyecto 801, DIPPR@, Instituto de Diseo para Datos de Propiedades Fsicas del Instituto Americano de Ingenieros Qumicos (AIChE) y reproducidos con permiso. La recopilacin de los datos completos est publicada por T. E. Daubert, R. P Danner, H. M. Sibul y C. C. Stebbins, Physical and Thwmodynamic Properties of Pure Chemicals: Data Compilation, Ihylor & Fkancis, Bristol, PA, 1 405 sustancias qumicas existentes, 1995. Se incluyen valores para 26 constantes fsicas, as como valores recuperados de parmetros en las ecuaciones para la dependencia con respecto a la temperatura de 13 propiedades termodinmicas y de transporte. Versiones electrnicas de los mismos autores incluyen:l

DIPPR@ Data Compilation of Pure Compound Properties, ASCII Files,

National Institute of Science and lbchnology, Standard Referente Data, Gaithersburg, MD, 1 458 sustancias qumicas existentes, 1995

l

DIPPR@ Data Compilation, Student DIPPR Database, Versin PC-

DOS, National Institute of Science and lbchnology, Standard Referente Data, Gaithersburg, MD, 100 sustancias qumicas comunes para fines de enseanza, 1995.

726

APNDICE B.

Propiedades de especies puras

Ihbla B.l:Masa molar w

Propiedades de especies purasTc/K P,/bar 45.99 48.72 42.48 37.96 33.70 30.25 27.40 24.90 22.90 21.10 36.48 25.68 45.02 40.73 37.85 34.71 50.40 46.65 40.43 42.43 41.00 31.40 40.00 42.77 43.50 Z, Vc cm3 mal-l 98.6 145.5 200.0 255. 313. 371. 428. 486. 544. 600. 262.7 468. 258. 308. 319. 368. 131. 188.4 239.3 233.8 237.7 354. 238.9 220.4 291. 113. 259. 316. 374. 427. 369. 376. 379. 352. 413. 502. 115. 154. 228. 286. 209. 267. 280. 329. Tr,/K 111.4 184.6 231.1 272.7 309.2 341.9 371.6 398.8 424.0 447.3 261.4 372.4 322.4 353.9 345.0 374.1 225.5 266.9 276.9 274.0 336.3 266.3 268.7 356.1 189.4 353.2 383.8 409.4 425.6 417.6 412.3 411.5 418.3 528.2 154.1 294.0 330.1 350.2 329.4 352.8 307.6 328.4

Metano 16.043 0.012 190.6 Etano 30.070 0.100 305.3 Propano 44.097 0.152 369.8 n-Butano 58.123 0.200 425.1 n-Pentano 72.150 0.252 469.7 n-Hexano 86.177 0.301 507.6 n-Heptano 100.204 0.350 540.2 n-Octano 114.231 0.400 568.7 n-Nonano 128.258 0.444 594.6 n-Decano 142.285 0.492 617.7 Isobutano 58.123 0.181 408.1 Isoctano 114.231 0.302 544.0 Ciclopentano 70.134 0.196 511.8 Ciclohexano 84.161 0.210 553.6 Metilciclopentano 84.161 0.230 532.8 Metilciclohexano 98.188 0.235 572.2 Etileno 28.054 0.087 282.3 Propileno 42.081 0.140 365.6 l-Buteno 56.108 0.191 420.0 cis-2-Buteno 56.108 0.205 435.6 truns-2-Buteno 56.108 0.218 428.6 1-Hexeno 84.161 0.280 504.0 Isobutileno 56.108 0.194 417.9 ,3-Butadieno 54.092 0.190 425.2 Ciclohexeno 82.145 0.212 560.4 Acetileno 26.038 0.187 308.3 78.114 0.210 562.2 Benceno Tolueno 92.141 0.262 591.8 Etilbenceno 106.167 0.303 617.2 Cumeno 120.194 0.326 631.1 o-Xileno 106.167 0.310 630.3 m-Xileno 106.167 0.326 617.1 p-Xileno 106.167 0.322 616.2 Estireno 104.152 0.297 636.0 Naftaleno 128.174 0.302 748.4 Bifenilo 154.211 0.365 789.3 firmaldehdo 30.026 0.282 408.0 Acetaldehdo 44.053 0.291 466.0 Acetato de metilo 74.079 0.331 506.6 Acetato de etilo 88.106 0.366 523.3 Acetona 58.080 0.307 508.2 Metil etil cetona 72.107 0.323 535.5 $ter dietlico 74.123 0.281 466.7 Eter metil t-butlico 88.150 0.266 497.1

0.286 0.279 0.276 0.274 0.270 0.266 0.261 0.256 0.252 0.247 0.282 0.266 0.273 0.273 0.272 0.269 0.281 0.289 0.277 0.273 0.275 0.265 0.275 0.267 0.272 61.39 0.271 48.98 0.271 41.06 0.264 36.06 0.263 32.09 0.261 37.34 0.263 35.36 0.259 35.11 0.260 38.40 0.256 40.51 0.269 38.50 0.295 65.90 0.223 55.50 0.221 47.50 0.257 38.80 0.255 47.01 0.233 41.50 0.249 36.40 0.263 34.30 0.273

169.4

727 YIbbla B.l: Propiedades de especies puras (Continuacin) Masa molar w T,/K 512.6 513.9 536.8 563.1 611.4 508.3 694.3 719.7 592.0 615.7 751.0 545.5 430.1 456.2 588.2 556.4 536.4 510.0 416.3 460.4 632.4 150.9 209.4 289.7 5.2 33.19 154.6 126.2 417.2 132.9 304.2 552.0 373.5 430.8 490.9 180.2 309.6 324.7 456.7 647.1 405.7 520.0 924.0 PJbar 80.97 61.48 51.75 44.23 35.10 47.62 61.30 77.00 57.86 40.64 44.70 48.30 74.60 56.20 63.10 45.60 54.72 60.80 66.80 52.70 45.20 48.98 55.02 58.40 2.28 13.13 50.43 34.00 77.10 34.99 73.83 79.00 89.63 78.84 82.10 64.80 72.45 83.10 53.90 220.55 112.80 68.90 64.00 2,

cm3 mal-l 118. 167. 219. 275. 381. 220. 229. 191.0 179.7 291.7 344. 173. 154. 207. 173. 276. 239. 185. 143. 200. 308. 74.6 91.2 118.0 57.3 64.1 73.4 89.2 124. 93.4 94.0 160. 98.5 122. 127. 58.0 97.4 81. 139. 55.9 72.5 145. 177.

V,

TJK337.9 351.4 370.4 390.8 430.6 355.4 455.0 470.5 391.1 436.4 522.4 354.8 266.8 289.7 374.4 349.8 334.3 312.9 249.1 285.4 404.9 87.3 119.8 165.0 4.2 20.4 90.2 77.3 239.1 81.7 319.4 212.8 263.1 317.9 121.4 184.7 188.2 298.9 373.2 239.7 356.2 610.0

Metano1 32.042 0.564 Etanol 46.069 0.645 l-Propano1 60.096 0.622 l-Butano1 74.123 0.594 1 -Hexano1 102.177 0.579 2-Propano1 60.096 0.668 Penol 94.113 0.444 Etilenglicol 62.068 0.487 cido actico 60.053 0.467 cido n-butrico 88.106 0.681 cido benzoico 122.123 0.603 Acetonitrilo 41.053 0.338 Metilamina 31.057 0.281 Etilamina 45.084 0.285 Nitrometano 61.040 0.348 !Ietracloruro de carbono 153.822 0.193 119.377 0.222 Cloroformo 84.932 Diclorometano 0.199 Cloruro de metilo 50.488 0.153 Cloruro de etilo 64.514 0.190 112.558 0.250 Clorobenceno Argn 39.948 0.000 83.800 0.000 Kriptn 165.03 Xenn 0.000 Helio 4 4.003 -0.390 Hidrgeno 2.016 -0.216 31.999 0.022 Oxgeno Nitrgeno 28.014 0.038 70.905 0.069 Cloro Monxido de carbono 28.010 0.048 44.010 0.224 Dixido de carbono Disulfuro de carbono 76.143 0.111 34.082 0.094 Sulfuro de hidrgeno Dixido de azufre 64.065 0.245 80.064 0.424 Trixido de azufre xido ntrico( NO) 30.006 0.583 44.013 0.141 xido nitroso( NsO) Cloruro de hidrgeno 36.461 0.132 Cianuro de hidrgeno 27.026 0.410 18.015 0.345 Agua Amoniaco 17.031 0.253 Acido ntrico 63.013 0.714 Acido sulfn-ico 98.080 ...

0.224 0.240 0.254 0.260 0.263 0.248 0.243 0.246 0.211 0.232 0.246 0.184 0.321 0.307 0.223 0.272 0.293 0.265 0.276 0.275 0.265 0.291 0.288 0.286 0.302 0.305 0.288 0.289 0.265 0.299 0.274 0.275 0.284. 0.269 0.255 0.251 0.274 0.249 0.197 0.229 0.242 0.231 0.147

A P NDICE C

CAPACIDADES CALORFICAS Y CAMBIOS DE PROPIEDADES < DE FORMACIN

Tabla C.l Igbla C.2 hbla C.3 lhbla C.4

Capacidades c.alor&s~ Capacidades caloritcas Capacidades caloriicas Entalpas

de gases en el estado de gas ideal de s6lidos de liquidos

esthndar y energas de Gibbs de formacin a 298.15 K

729

hbla C.l:Constantes enlaecuacin Especie qumica

Capacidades caIor&asTdXCH4 C2Hs C3& C4H10 C4H10 C5H12 C6H14

de gases en estado de gas ideal+T (kelvins) de 298 a T,,,exlo3

C$/R =A + BT + CT2 + D!F2 A1.702 1.131 1.213 1.935 1.677 2.464 3.025 3.570 8.163 1.424 1.637 1.967 2.691 3.220 3.768 4.324 1.693 6.132 -0.206 2.734 -3.876 3.518 1.124 -0.385 2.264 2.211 0.290 2.050 3.355 3.578 4.493 3.376 5.457 6.311 4.442 3.249 3.931 3.156 4.736 3.280 5.328 3.387 4.982 11.660 3.639 5.699 8.060 3.470

B

10s c -2.164 -5.561 -8.824 -11.402 -11.945 -14.111 -16.791 -19.486 -22.208 -4.392 -6.915 -9.873 -12.447 -15.157 -17.847 -20.521 -6.158 . . . < -13.301 -8.882 -20.928 -6.002 -18.476 -9.296 -1.877 -3.450 -15.716 -16.662

lo5

D

Parafinas: Metano Etano Propano n-Butano iso-Butano n-Pentano n-Hexano n-Heptano n-Octano l-Alquenos: Etileno Propileno l-Buteno l-Penteno 1-Hexeno 1-Hepteno l-Octeno Sustancias org&nicas Acetaldehido Acetileno Benceno 1,3-Butadieno Ciclohexano Etanol Etilbenceno 6xido de etileno Fxmaldehdo Metano1 Tolueno Estireno

Xb &HlsC2H4 C3H6 C4H6 C5H10 C6H12 GH14 CeH16

1500 1500 1500 1500 1500 1500 1500 1500 1500 1500 1500 1500 1500 1500 1500 1500 1000 1500 1500 1500 1500 1500 1500 1000 1500 1500 1500 1500 2000 1800 2500 2000 3000 3000 2300 2000 2500 2000 2000

9.081 19.225 28.785 36.915 37.853 45.351 53.722 62.127 70.567 14.394 22.706 31.630 39.753 48.189 56.588 64.960 17.978 1.952 39.064 26.786 63.249 20.001 55.380 23.463 7.022 12.216 47.052 50.192 0.575 3.020 0.056 0.557 1.045 0.805 0.089 0.422 1.490 0.623 1.359 0.593 1.214 0.629 1.195 2.257 0.506 0.801 1.056 1.450

miscelneas:C2H40 C2H2 C6H6 C4H6 C6H12 C2H60

-1.299

CsHloC2H40

CH20 CH40 GHs CsHs

Sustancias inorg&nicas miscel&neas: Aire Amoniaco NH, Bromo Br2 Monxido de carbono co Dixido de carbono co2 Disulfuro de carbono CS Cloro Cl2 Hidrgeno H2 Sulfuro dc hidrgeno H2S Cloruro de hidrgeno HCI Cianuro de hidrgeno HCN Nitrgeno N2 xido nitroso N2O xido ntrico NO Dixido de nitrgeno NO2 Tetrxido de dinitrgeno N204 Oxigeno 02 Dixido de azufre se? liixido de azufre so3 Agua Hz0 %eleceionado

...... ...... ...... ...... ...... ...... ...... ...... ...... ...... ...... ...... ...... ...... ...... ...... ...... ...... ...... .

-0.016 -0.186 -0.154 -0.031 -1.157 4.906 -0.344 0.083 4.232 0.151 -0.725 0.040 -0.928 0.014 -0.792 -2.787 -0.227 -1.015 -2.028 0.121

de H. M. Spenw, Ind. Eng. ches., val. 40, pp. 2152-2X4,1948; K. K. Kelley, U.S.

Bur

Mines Bd.?. 584,1960;L.B.Pankratz,U.S. Bul: MinesBulL 672,1982.

730

APNLIICE C.

Capacidades calorficas y cambios de propiedades de formacin

lhbla C.2:

Capacidades calor&as de s6lidostBT + DT21O-5

Constantes para la ecuacin CdR = A + T(kelvins) de 298 K a T,,,k Esnecie aumica Ca0 CaCOs Ca (OH)2 CaCs CaClz C (grafito) CU ch0 Fe (4Fe203 Fe304

T,A2000 1200 700 720 1055 2000 1357 1400 1043 960 850 411 386.8 458 371 1073 566 400 368.3 847

A6.104 12.572 9.597 8.254 8.646 1.771 2.677 5.780 -0.111 11.812 9.594 2.612 6.481 5.939 1.988 5.526 0.121 5.128 4.114 4.871

lo3 B0.443 2.637 5.435 1.429 1.530 0.771 0.815 0.973 6.111 9.697 27.112 13.286 1.502 16.105 4.688 1.963 16.316 18.148 -1.728 5.365

D

-1.047 -3.120 -1.042 -0.302 -0.867 0.035 -0.874 1.150 -1.976 0.409

FeS12

NH&1 Na NaCl NaOH NaHCOs S (rmbico) SiOz (cuarzo)

1.948 -0.783 -1.001

+Seleccionados de K. K. Kelley, U. S. Bur Mina U. S.Bur MiwsBull. 672, 1982.

BuU. 584,196O; L. B. Pankratz,

!hbla C.3:

Capacidades calorficas de lquidos+BT + CT 2106 c 192.71 -15.80 -37.78 205.79 101.14 -31.90 83.01 -161.62 349.17 172.28 131.13 427.20 -84.73 16.35 -0.18

Constantes para la ecuacin Cp/R = A + T de 273.15 a 373.15 K Especie qumica Amoniaco Anilina Benceno ,3-Butadieno Tetracloruro de carbono Clorobenceno Cloroformo Ciclohexano Etanol xido de etileno Metano1 n-Propano1 Trixido de azufre Tolueno Ma

A22.626 15.819 -0.747 22.711 21.155 ll.278 19.215 -9.048 33.866 21.039 13.431 41.653 -2.930 15.133 8.712

lo3

B

-100.75 29.03 67.96 -87.96 -48.28 32.86 42.89 141.38 -172.60 -86.41 -51.28 -210.32 137.08 6.79 1.25

+Basado en las correlaciones presentadas por J. W Miller, Jr., G. R. Schorry C. L. Yaws, ti. Eng., vol. 83(23), p. 129,1976.

731

Tabla C.4:

Entalpas estndar y energas de Gibbs de formacinJoules por mol de la sustancia formada Estado (Nota 2)

a 298.15 ti

Especie qumica Parafinas: Metano Etano Propano n-Butano n-Pentano wHexano n-Heptano n-Octano 1-Alquenos: Etileno Propileno l-Buteno 1-Penteno 1-Hexeno l-Hepteno

CH4

2%C3He C4H10 C5H12 Cd%4 M14

WIG

-74 -83 -104 -125 -146 -166 -187 -208

520 820 680 790 760 920 780 750

-50 460 -31855 -24 290 -16 570 -8 650 150 8 260 16 260

C2H4 C3JJs C4He C5H10 GH12 GH14

52 510 19 710 -540 -21280 -41950 -62 760

68 62 70 78 86

460 205 340 410 830

Sustancias orgzinicas miscel&neas: Acetaldehido (AH40 cido actico C2H402 Acetileno C2H2 Benceno Gas Benceno CsHs 1,3-Butadieno C4H6 Ciclohexano C6H12 Ciclohexano C6H12 1,2-Etanodiol C2H602 Etanol C2H60 Etanol caso Etilbenceno Cs&o xido de etileno C2H40 lkmaldehdo CH20 Metano1 CH40 Metano1 CH40 Metilciclohexano GH14 Metilciclohexano GH14 Estireno Gas Tolueno CIHB Tolueno GHs

-166 190 -484 500 227 480 82 930 49 080 109 240 -123 140 -156 230 -454 800 -235 100 -277 690 29 920 -52 630 -108 570 -200 660 -238 660 -154 770 -190 160 147 360 50 170 12 180

-128 860 -389 900 209 970 129 665 124 520 149 795 31920 26 850 -323 080 -168 490 -174 780 130 890 -13 010 -102 530 -161960 -166 270 27 480 20 560 213 900 122 050 113 630

732

APNDICE C.

Capacidades calorficas y cambios de propiedades de formacin Ihbla C.4 (Continuacin)Estado (Nota 2) miscelneas:

Especie

qumica

Sustancias inor&icas

Amoniaco Carburo de calcio Carbonato de calcio Cloruro de calcio Cloruro de calcio Cloruro de calcio Hidrxido de calcio Hidrxido de calcio 6xido de calcio Dixido de carbono Monxido de carbono cido clorhdrico Cianuro de hidrgeno Sulfuro de hidrgeno 6xido de hierro xido de hierro (hematita) xido de hierro (magnetita) Sulfuro de hierro (pirita) Cloruro de litio Cloruro de litio Cloruro de litio Cloruro de litio cido nitrito cido ntrico xidos de nitrgeno

NH3 NH3

-46 110 -59 800 -1206 920 -795 800 -2 607 900 -986 090 -635 090 -393 509 -110 525 -92 307 135 100 -20 630 -272 000 -824 200 -1118 400 -178 200 -408 610 -712 580 -1012 650 -1311300 -174 100 90 250 33 180 82 050 9 160 -1 130 680 4 081320 -411 153 -425 609 -296 830 -395 720 -441040 -813 989 -241818 -285 830

CaCs CaCO CaC CaCls CaCly6HsO Ca(OHh Ca Ca0co2

-16 450 -26 500 -64 900 -1128 790 -748 100 -8 101900 -898 -868 -604 -394 -137 -95 124 -33 490 070 030 359 169 299 700 560

co

HCl HCNH2S

FC?0Fe203 Fe304 RS2

-742 200 -1015 400 -166 900

Lic1 LiChHsO LiCh2HsO LiCh3HsO HNOs HNO, NONOn N2O N204

Carbonato de sodio Carbonato de sodio Cloruro de sodio Cloruro de sodio Hidrxido de sodio Hidrxido de sodio Dixido de azufre nixido de azufre Trixido de azufre cido sulfrico cido sulfrico Agua Agua

Na&03 NasCOs.lOHsO NaCl NaCl NaOH NaOHso2 so3 so3 H2S04 H2S04 Hz0

-80 710 -111250 86 550 51310 104 200 97 540 -1044 440 -384 138 -393 133 -379 494 419 150 -300 194 -371060 -690 -744 -228 -237 003 530 572 129

Hz0

%bmado de TRC Thermodynamic !llzbles-Hydmarbons, Thermodynamics Ftesearch Center, Texas A & M Unir. System, College Station, Texas; The NBS Ihbles of Chemical Thermodynamic Properties, J. Physkal and Chemica Refem Data, vol. 11, sup. 2, 1982. Notas 1. La energa estndar de Gibbs de formacin AG& es el cambio en la energa de Gibbs, cuando 1 mol del compuesto enlistado se forma a partir de sus elementos con cada sustancia en su estado esmndar a 298.15 K (25C). 2 . Estados estndar: (a) Gases @): el gas ideal puro a 1 bar y 25C. (b) Lquidos (Z) y slidos . (s): la sustancia pura a 1 bar y 25C. (c) Solutos en solucin acuosa (oc): La solucin ideal hipotktica 1-molal del soluto en agua a 1 bar y 25C.

A P NDICE E

TABLAS DE CORRELACIN GENERALIZADA DE LEE/ KESLER

Las tablas de Lee/Kesler se han adaptado y publicado con permiso de A Generalized Thermodynamic Correlation based on Three-Parameter Corresponding States, por Byung Ik Lee y Michael G. Kesler, HChE J., 21, 510-527 (1975). Los nmeros impresos en itlicas son propiedades de la fase lquida.

!lhblas EJ-E.4 lhblas E.5-E.8 lhblas E.9-E. 12

Correlacin para el factor de compresibilidad Correlacin para la entalpa residual Correlacin para la entropa residual Correlacin para el coeficiente de fugacidad

Iltblas E. 13-E. 16

742

APNDICE E.

Tablas de correlacin generalizada de Le&esler

lhbla E. 1: Valores de ZP, =

0.0100 0.0029 0.0026 0.0024 0.0022 0.0021 0.9804 0.9849 0.9881 0.9904 0.9922 0.9935 0.9946 0.9954 0.9959 0.9961 0.9963 0.9965 0.9966 0.9967 0.9968 0.9969 0.9971 0.9975 0.9978 0.9981 0.9985 0.9988 0.9991 0.9993 0.9994 0.9995 0.9996 0.9997 0.9998 0.9999 1.0000 1.0000 1.0000 1.0001 1.0001

0.05000.0145 0.0130 0.0119 0.0110 0.0103 0.0098 0.0093 0.9377 0.9504 0.9598 0.9669 0.9725 0.9768 0.9790 0.9803

0.10000.0290 0.0261 0.0239 0.0221

0.2000 0.0579 0.0522 0.0477 0.04420.0413 0.0390 0.0371

0.40000.1158 0.1043 0.0953

0.60000.1737 0.1564 0.1429 0.1322 0.1236 0.1166 0.1109 0.1063 0.1027 0.1001 0.0985 0.0983 0.1006 0.6635 0.6967 0.7240 0.7360

0.80000.2315 0.2084 0.1904 0.1762 0.1647 0.1553 0.1476 0.1415 0.1366 0.1330 0.1307 0.1301 0.1321 0.1359 0.1410

1.00000.2892 0.2604 0.2379 0.2200 0.2056

0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.93 0.95 0.97 0.98 0.99 1.00 1.01 1.02 1.05 1.10 1.15 1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.20 2.40 2.60 2.80 3.00 3.50 4.00

0.02070.0195 0.0186 0.0178 0.8958

0.0882 0.0825 0.07780.0741 0.0710

0.19390.1842

0.9815 0.9821 0.9826 0.9832 0.9837 0.9842 0.9855 0.9874 0.9891 0.9904 0.9926 0.9942 0.9954 0.9964 0.9971 0.9977 0.9982 0.9986 0.9992 0.9996 0.9998 1.0000 1.0002 1.0004 1.0005

0.9165 0.9319 0.9436 0.9528 0.9573 0.9600 0.9625 0.9637 0.9648 0.9659 0.9669 0.9679 0.9707 0.9747 0.9780 0.9808 0.9852 0.9884 0.9909 0.9928 0.9943 0.9955 0.9964 0.9972 0.9983 0.9991 0.9997 1.0001 1.0004 1.0008 1.0010

0.0356 0.0344 0.0336 0.8539 0.8810 0.9015 0.9115 0.9174 0.9227 0.9253 0.9277 0.9300 0.9322 0.9343 0.9401 0.9485 0.9554 0.9611 0.9702 0.9768 0.9818 0.9856 0.9886 0.9910 0.9929 0.9944 0.9967 0.9983 0.9994 1.0002 1.0008 1.0017 1.0021

0.0687 0.06700.0661 0.0661 0.7800 0.8059 0.8206 0.8338 0.8398 0.8455 0.8509

0.8561 0.8610 0.8743 0.8930 0.9081 0.9205 0.9396 0.9534 0.9636 0.9714 0.9775 0.9823 0.9861 0.9892 0.9937 0.9969 0.9991 1.0007 1.0018 1.00351.0043

0.7471 0.7574 0.7671 0.7761 0.8002 0.8323 0.8576 0.8779 0.9083 0.9298 0.9456 0.9575 0.9667 0.9739 0.9796 0.9842 0.9910 0.9957 0.9990 1.0013 1.0030 1.0055 1.0066

0.1765 0.1703 0.1656 0.1626 0.1614 0.1630 0.1664 0.1705 0.5580 0.1779 0.5887 0.1844 0.6138 0.1959 0.6355 0.29010.6542 0.4648

0.6710 0.7130 0.7649 0.8032 0.8330 0.8764 0.9062 0.9278 0.9439 0.9563 0.9659 0.9735 0.9796 0.9886 0.9948 0.9990 1.0021 1.0043 1.0075 1.0090

0.5146 0.6026 0.6880 0.7443 0.7858 0.8438 0.8827 0.9103 0.9308 0.9463 0.9583 0.9678 0.9754 0.9865 0.9941 0.9993 1.0031 1.0057 1.0097 1.0115

743

!Jbbla E.2: Valores de Z1P, =

0.0100

0.0500

0.1000-0.0081 -0.0093 -0.0095 - 0.0094 - 0.0090

0.2000-0.0161 -0.0185 -0.0190 -0.0187 -0.0181 -0.0172

0.4000

0.6000

0.8000

1.0000

0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.93 0.95 0.97 0.98 0.99 1.00 1.01 1.02 1.05 1.10 1.15 1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.20 2.40 2.60 2.80 3.00 3.50 4.00

;0.0008 -0.0040 -0.0009 -0.0046 -0.0010 -0.0048 -0.0009 -0.0047 -0.0009 -0.0045 -0.0314 -0.0043 -0.0205 -0.0041 -0.0137 -0.0772 -0.0093 -0.0507 -0.0064 -0.0339 -0.0044 -0.0228 -0.0029 -0.0152 -0.0019 -0.0099 -0.0015 -0.0075 -0.0012 -0.0062 -0.0010 -0.0050 -0.0009 -0.0044 -0.0008 -0.0039 -0.0007 -0.0034 -0.0006 -0.0030 -0.0005 -0.0026 -0.0003 -0.0015 0.0000 0.0000 0.0002 0.0011 0.0019 0.0004 0.0006 0.0030 0.0007 0.0036 0.0008 0.0039 0.0008 0.0040 0.0008 0.0040 0.0008 0.0040 0.0008 0.0040 0.0008 0.0039 0.0007 0.0037 0.0007 0.0035 0.0007 0.0033 0.0006 0.0031 0.0006 0.0029 0.0005 0.0026 0.0005 0.0023

-0.0086 -0.0082 -0.0078 -0.1161 -0.0744 -0.0487 -0.0319 -0.0205 -0.0154 -0.0126 -0.0101 -0.0090 -0.0079 -0.0069 -0.0060 -0.0051 -0.0029 0.0001 0.0023 0.0039 0.0061 0.0072 0.0078 0.0080 0.0081 0.0081 0.0079 0.0078 0.0074 0.0070 0.0066 0.0062 0.0059 0.0052 0.0046

-0.0164-0.0156 -0.0148 -0.0143

-0.1160 -0.0715 - 0.0268 -0.0442 -0.1118 -0.0326 -0.0763 -0.0262 -0.0589 -0.0208 -0.0450 -0.0184 -0.0390 -0.0161 -0.0335 -0.0140 -0.0285 -0.0120 -0.0240 -0.0102 -0.0198 -0.0054 -0.0092 0.0007 0.0038 0.0052 0.0127 0.0190 0.0084 0.0125 0.0267 0.0147 0.0306 0.0158 0.0323 0.0162 0.0330 0.0163 0.0329 0.0162 0.0325 0.0159 0.0318 0.0155 0.0310 0.0147 0.0293 0.0139 0.0276 0.0131 0.0260 0.0124 0.0245 0.0117 0.0232 0.0103 0.0204 0.0091 0.0182

-0.0323 -0.0484 -0.0645 -0.0806 -0.0370 -0.0554 -0.0738 -0.0921 -0.0380 -0.0570 -0.0758 -0.0946 -0.0374 -0.0560 -0.0745 -0.0929 -0.0360 -0.0539 -0.0716 -0.0893 -0.0343 -0.0513 -0.0682 -0.0849 -0.0326 -0.0487 -0.0646 -0.0803 -0.0309 -0.0461 -0.0611 -0.0759 -0.0294 -0.0438 -0.0579 -0.0718 -0.0282 -0.0417 -0.0550 -0.0681 -0:0272 -0.0401 -0.0526 -0.0648- 0.0391 - 0.0509 -0.0622

-0.0396 -0.0503 -0.0604 -0.1662 -0.0514 -0.0602 -0.1110 -0.0540 -0.0607 -0.0770 -0.1647 -0.0623 -0.0641 -0.1100 -0.0641 -0.0531 -0.0796 -0.0680 -0.0435 -0.0588 -0.0879 -0.0351 -0.0429 -0.0223 -0.0277 -0.0303 -0.0062 -0.0097 -0.0032 0.0220 0.0106 0.0236 0.0476 0.0237 0.0396 0.0625 0.0326 0.0499 0.0719 0.0429 0.0612 0.0819 0.0477 0.0661 0.0857 0.0497 0.0677 0.0864 0.0501 0.0677 0.0855 0.0497 0.0667 0.0838 0.0488 0.0652 0.0814 0.0477 0.0635 0.0792 0.0464 0.0617 0.0767 0.0437 0.0579 0.0719 0.0411 0.0544 0.0675 0.0387 0.0512 0.0634 0.0365 0.0483 0.0598 0.0345 0.0456 0.0565 0.0303 0.0401 0.0497 0.0270 0.0443 0.0357

744

APNDICE E.

Tablas de correlacin generalizada de Le&Kesler

Ihbla E.3: Valores de 2P, = 1.0000 TT

1.20000.3479

1.5000 0.4335 0.3901 0.3563 0.3294 0.3077 0.2899 0.2753 0.2634 0.2538 0.2464 0.2411 0.2382 0.2383 0.2405 0.2432 0.2474 0.2503 0.2538 0.2583 0.2640 0.2715 0.3131 0.4580 0.5798 0.6605 0.7624 0.8256 0.8689 0.9000 0.9234 0.9413 0.9552 0.9664 0.9826 0.9935 1.0010 1.0063 1.0101 1.0156 1.0179

2.0000 0.5775 0.5195 0.4744 0.4384 0.4092 0.3853 0.3657 0.3495 0.3364 0.3260 0.3182 0.3132 0.3114 0.3122 0.3138 0.3164 0.3182 0.3204 0.3229 0.3260 0.3297 0.3452 0.3953 0.4760 0.5605 0.6908 0.7753 0.8328 0.8738 0.9043 0.9275 0.9456 0.9599 0.9806 0.9945 1.0040 1.0106 1.0153 1.0221 1.0249

3.0000 0.8648 0.7775 0.7095 0.6551 0.6110 0.5747 0.5446 0.5197 0.4991 0.4823 0.4690 0.4591 0.4527 0.4507 0.4501 0.4504 0.4508 0.4514 0.4522 0.4533 0.4547 0.4604 0.4770 0.5042 0.5425 0.6344 0.7202 0.7887 0.8410 0.8809 0.9118 0.9359 0.9550 0.9827 1.0011 1.0137 1.0223 1.0284 1.0368 1.0401

5.0000 1.4366 1.2902 1.1758 1.0841 1.0094 0.9475 0.8959 0.8526 0.8161 0.7854 0.7598 0.7388 0.7220 0.7138 0.7092 0.7052 0.7035 0.7018 0.7004 0.6991 0.6980 0.6956 0.6950 0.6987 0.7069 0.7358 0.7761 0.8200 0.8617 0.8984 0.9297 0.9557 0.9772 1.0094 1.0313 1.0463 1.0565 1.0635 1.0723 1.0747

7.0000 2.0048 1.7987 1.6373 1.5077 1.4017 1.3137 1.2398 1.1773 1.1341 1.0787 1.0400 1.0071 0.9793 0.9648 0.9561 0.9480 0.9442 0.9406 0.9372 0.9339 0.9307 0.9222 0.9110 0.9033 0.8990 0.8998 0.9112 0.9297 0.9518 0.9745 0.9961 1.0157 1.0328 1.0600 1.0793 1.0926 1.1016 1.1075 1.1138 1.1136

10.000 2.8507 2.5539 2.3211 2.1338 1.9801 1.8520 1.7440 1.6519 1.5729 1.5047 1.4456 1.3943 1.3496 1.3257 1.3108 1.2968 1.2901 1.2835 1.2772 1.2710 1.2650 1.2481 1.2232 1.2021 1.1844 1.1580 1.1419 1.1339 1.1320 1.1343 1.1391 1.1452 1.1516 1.1635 1.1728 1.1792 1.1830 1.1848 1.1834 1.1773

0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.93 0.95 0.97 0.98 0.99 1.00 1.01 1.02 1.05 1.10 1.15 1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.20 2.40 2.60 2.80 3.00 3.50 4.00

0.2892 0.2604 0.2379 0.2200 0.2056 0.1939 0.1842 0.1765 0.1703 0.1656 0.1626 0.1614 0.1630 0.1664 0.1705 0.1779 0.1844 0.1959 0.2901 0.4648 0.5146 0.6026 0.6880 0.7443 0.7858 0.8438 0.8827 0.91.03 0.9308 0.9463 0.9583 0.9678 0.9754 0.9856 0.9941 0.9993 1.0031 1.0057 1.0097 1.0115

0.3123 0.2853 0.2638 0.2465 0.2323 0.2207 0.2113 0.2038 0.1981 0.1942 0.1924 0.1935 0.1963 0.1998 0.2055 0.2097 0.2154 0.2237 0.2370 0.2629 0.4437 0.5984 0.6803 0.7363 0.8111 0.8595 0.8933 0.9180 0.9367 0.9511 0.9624 0.9715 0.9847 0.9936 0.9998 1.0042 1.0074 1.0120 1.0140

745

Ilabla E. 4: Viores de Z1P, = T,

1.0000 -0.0806 -0.0921 -0.0946 -0.0929 -0.0893 -0.0849 -0.0803 -0.0759 -0.0718 -0.0681 -0.0648 -0.0622 -0.0604 -0.0602 -0.0607 -0.0623 -0.0641 -0.0680 -0.0879 -0.0223 -0.0062 0.0220 0.0476 0.0625 0.0719 0.0819 0.0857 0.0854 0.0855 0.0838 0.0816 0.0792 0.0767 0.0719 0.0675 0.0634 0.0598 0.0535 0.0497 0.0443

1.2000 -0.0966 -0.1105 -0.1134 -0.1113 -0.1069 -0.1015 -0.0960 -0.0906 -0.0855 -0.0808 -0.0767 -0.0731 -0.0701 -0.0687 -0.0678 -0.0669 -0.0661 -0.0646 -0.0609 -0.0473 -0.0227 0.1059 0.0897 0.0943 0.0991 0.1048 0.1063 0.1055 0.1035 0.1008 0.0978 0.0947 0.0916 0.0857 0.0803 0.0754 0.0711 0.0672 0.0591 0.0527

1.5000 -0.1207 -0.1379 -0.1414 -0.1387 -0.1330 -0.1263 -0.1192 -0.1122 -0.1057 -0.0996 -0.0940 -0.0888 -0.0840 -0.0810 -0.0788 -0.0759 -0.0740 -0.0715 -0.0678 -0.0621 -0.0524 0.0451 0.1630 0.1548 0.1477 0.1420 0.1383 0.1345 0.1303 0.1259 0.1216 0.1173 0.1133 0.1057 0.0989 0.0929 0.0876 0.0828 0.0728 0.0651

2.0000 -0.1608 -0.1834 -0.1879 -0.1840 -0.1762 -0.1669 -0.1572 -0.1476 -0.1385 -0.1298 -0.1217 -0.1138 -0.1059 -0.1007 -0.0967 -0.0921 -0.0893 -0.0861 -0.0824 -0.0778 -0.0722 -0.0432 0.0698 0.1667 0.1990 0.1991 0.1894 0.1806 0.1729 0.1658 0.1593 0.1532 0.1476 0.1374 0.1285 0.1207 0.1138 0.1076 0.0949 0.0849

3.0000 -0.2407 -0.2738 -0.2799 -0.2734 -0.2611 -0.2465 -0.2312 -0.2160 -0.2013 -0.1872 -0.1736 -0.1602 -0.1463 -0.1374 -0.1310 -0.1240 -0.1202 -0.1162 -0.1118 -0.1072 -0.1021 -0.0838 -0.0373 0.0332 0.1095 0.2079 0.2397 0.2433 0.2381 0.2305 0.2224 0.2144 0.2069 0.1932 0.1812 0.1706 0.1613 0.1529 0.1356 0.1219

5.0000 -0.3996 -0.4523 -0.4603 -0.4475 -0.4253 -0.3991 -0.3718 -0.3447 -0.3184 -0.2929 -0.2682 -0.2439 -0.2195 -0.2045 -0.1943 -0.1837 -0.1783 -0.1728 -0.1672 -0.1615 -0.1556 -0.1370 -0.1021 -0.0611 -0.0141 0.0875 0.1737 0.2309 0.2631 0.2788 0.2846 0.2848 0.2819 0.2720 0.2602 0.2484 0.2372 0.2268 0.2042 0.1857

7.0000 -0.5572 -0.6279 -0.6365 -0.6162 -0.5831 -0.5446 -0.5047 -0.4653 -0.4270 -0.3901 -0.3545 -0.3201 -0.2862 -0.2661 -0.2526 -0.2391 -0.2322 -0.2254 -0.2185 -0.2116 -0.2047 -0.1835 -0.1469 -0.1084 -0.0678 0.0176 0.1008 0.1717 0.2255 0.2628 0.2871 0.3017 0.3097 0.3135 0.3089 0.3009 0.2915 0.2817 0.2584 0.2378

10.000 -0.7915 -0.8863 -0.8936 -0.8608 -0.8099 -0.7521 -0.6928 -0.6346 -0.5785 -0.5250 -0.4740 -0.4254 -0.3788 -0.3516 -0.3339 -0.3163 -0.3075 -0.2989 -0.2902 -0.2816 -0.2731 -0.2476 -0.2056 -0.1642 -0.1231 -0.0423 0.0350 0.1058 0.1673 0.2179 0.2576 0.2876 0.3096 0.3355 0.3459 0.3475 0.3443 0.3385 0.3194 0.2994

0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.93 0.95 0.97 0.98 0.99 1.00 1.01 1.02 1.05 1.10 1.15 1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.20 2.40 2.60 2.80 3.00 3.50 4.00