Constantes de equilibrio7COMPONENTEFORMULATmaxESTADOABCDHfGfreactantes-147C2H41500GASEOSO1.4240.014394-0.0000043920-52510-68460-111H2O2000GASEOSO3.470.00145012100241818228572144C2H6O1500GASEOSO3.5180.020001-0.0000060020-235100-16849001-00000001-000000productos11-0000000001-00000001-00000001-00000001-000000-1.3760.004157-0.00000161-12100-45792-8378A=.AB=.BC=.CD=.D

18.314t=1.9894348482constantes de equilibrioTo ( K)25298.15
MANYASOLUTIONS: To: desplazar hasta la temperatura inicial, generalmente es 298 K1era integral22.6319325821K0
MANYASOLUTIONS: Ko: representa la constante de equilibrio a la temperatura de referencia29.3659306331T ( K)25593.15
MANYASOLUTIONS: T: desplazar hasta la temperatura final de la reaccion2da integral0.0173080298K1
MANYASOLUTIONS: K1:es un multiplicador que proporciona el principal efecto de temperatura0.0001022997G/RT=5.8286161021K2
MANYASOLUTIONS: K2: considera la influencia, mucho mas pequea, de la temperatura que resulta del cambio de H con la misma0.9793683398K0.0029421458K0.0029421458

1era integralIDCPH2da integralIDCPS

Tabla

Datos de Smith, van Ness,7ma. ed. FORMULANUMEROCOMPONENTE

J/mol T en [K], CP en [J/mol K]J/mol(DHf)(A)(B)(C)(D)estado(Gf)0-R11,3-BUTADIENO(g)C4H615001092402.3740.026786-0.0000088820GASEOSO14979518.314J/mol K21,3-BUTADIENO(l)C4H6373.15nd22.711-0.087960.000205790LIQUIDOnd28.314m3 Pa/mol K31-BUTENOC4H81500-5401.9670.031630-0.0000098730GASEOSO70340383.14cm3 bar/mol K41-HEPTENOC7H141500-627603.7680.056588-0.0000178470GASEOSOnd48.314cm3 kPa/mol K51-HEXENOC6H121500-419503.2200.048189-0.0000151570GASEOSO86830582.06cm3 atm/mol K61-OCTENOC8H161500nd4.3240.064960-0.0000205210GASEOSOnd662.356cm3 torr/mol K71-PENTENOC5H101500-212802.6910.039753-0.0000124470GASEOSO78410111.545ft lbf/lb mol R8ACETALDEHIDOC2H4O1000-1661901.6930.017978-0.0000061580GASEOSO-1288609ACETILENOC2H215002274806.1320.0019520-129900GASEOSO20997010AGUA(g)H2O2000-2418183.4700.001450012100GASEOSO-22857211AGUA(l)H2O373.15-2858308.7120.00125-0.000000180LIQUIDO-23712912AIRE-2000nd3.3550.0005750-1600GASEOSOnd13AMONIACO(g)NH31800-461103.5780.0030200-18600GASEOSO-1645014AMONIACO(l)NH3373.15nd22.626-0.100750.000192710LIQUIDOnd15ANILINA-373.15nd15.8190.02903-0.000015800LIQUIDOnd16AZUFRE(rombico)S368.304.1140.001450-78300SOLIDOnd17BENCENO(g)C6H6150082930-0.2060.039064-0.0000133010GASEOSO12966518BENCENO(l)C6H6373.1549080-0.7470.06796-0.000037780LIQUIDO12452019BICARBONATO DE SODIONaHCO3400nd5.1280.01814800SOLIDOnd20BROMOBR2300004.4930.0000560-15400GASEOSOnd21CARBONATO DE CALCIOCaCO31200-120692012.5720.0026370-312000SOLIDO-112879022CARBURO DE CALCIOCaC2720-598008.2540.0014290-104200SOLIDO-6490023CIANURO DE HIDROGENOHCN25001351004.7360.0013590-72500GASEOSO12470024CICLOHEXANO(g)C6H121500-123140-3.8760.063249-0.0000209280GASEOSO3192025CICLOHEXANO(l)C6H12373.15-156230-9.0480.14138-0.000161620LIQUIDO2685026CLOROCl2300004.4420.0000890-34400GASEOSOnd27CLOROBENCENO-373.15nd11.2780.03286-0.000031900LIQUIDOnd28CLOROFORMO-373.15nd19.215-0.042890.000083010LIQUIDOnd29CLORURO DE AMONIONH4Cl458nd5.9390.01610500SOLIDOnd30CLORURO DE CALCIOCaCl21055-7958008.6460.0015300-30200SOLIDO-74810031CLORURO DE HIDROGENOHCl2000-923073.1560.000623015100GASEOSOnd32CLORURO DE LITIOLiCl800-4086105.2570.0024760-19300SOLIDOnd33CLORURO DE SODIONaCl1073-4111535.5260.00196300SOLIDO-38413834COBRECu135702.6770.00081503500SOLIDOnd35DIHIDROXIDO DE CALCIOCa(OH)2700-9860909.5970.00543500SOLIDOnd36DIOXIDO DE AZUFRESO22000-2968305.6990.0008010-101500GASEOSO-30019437DIOXIDO DE CARBONOCO22000-3935095.4570.0010450-115700GASEOSO-39435938DIOXIDO DE NITROGENONO22000331804.9820.0011950-79200GASEOSOnd39DIOXIDO DE SILICIO(cuarzo)SiO2847nd4.8710.0053650-100100SOLIDOnd40DISULFURO DE CARBONOCS21800nd6.3110.0008050-90600GASEOSOnd41ESTIRENOC8H81500nd2.0500.050192-0.0000166620GASEOSO21390042ETANOC2H61500-838201.1310.019225-0.0000055610GASEOSO-3185543ETANOL(g)C2H6O1500-2351003.5180.020001-0.0000060020GASEOSO-16849044ETANOL(l)C2H6O373.15-27769033.866-0.172600.000349170LIQUIDO-17478045ETILBENCENOC8H101500nd1.1240.055380-0.0000184760GASEOSO13089046ETILENOC2H41500525101.4240.014394-0.0000043920GASEOSO6846047FORMALDEHIDOCH2O1500-1085702.2640.007022-0.0000018770GASEOSO-10253048GRAFITOC200001.7710.0007710-86700SOLIDOnd49HIDROGENOH2300003.2490.00042208300GASEOSOnd50HIDROXIDO DE SODIONaOH566-4256090.1210.0163160194800SOLIDO-37949451HIERROFe()10430-0.1110.0061110115000SOLIDOnd52iso-BUTANOC4H101500nd1.6770.037853-0.0000119450GASEOSOnd53METANOCH41500-745201.7020.009081-0.0000021640GASEOSO-5046054METANOL(g)CH4O1500-2006602.2110.012216-0.0000034500GASEOSO-16196055METANOL(l)CH4O373.15-23866013.431-0.051280.000131130LIQUIDO-16627056MONOXIDO DE CARBONOCO2500-1105253.3760.0005570-3100GASEOSO-13716957n-BUTANOC4H101500-1257901.9350.036915-0.0000114020GASEOSO-1657058n-HEPTANOC7H141500-1877803.5700.062127-0.0000194860GASEOSO826059n-HEXANOC6H141500-1669203.0250.053772-0.0000167910GASEOSO15060NITROGENON2200003.2800.00059304000GASEOSOnd61n-OCTANOC8H181500-2087504.1080.070567-0.0000222080GASEOSO1626062n-PENTANOC5H121500-1467602.4640.045351-0.0000141110GASEOSO-865063n-PROPANOL-373.15nd41.653-0.210320.000427200LIQUIDOnd64OXIDO DE CALCIOCaO2000-6350906.1040.0004430-104700SOLIDO-60403065OXIDO DE COBRECuO1400nd5.7800.0009730-87400SOLIDOnd66OXIDO DE ETILENO(g)C2H4O1000-52630-0.3850.023463-0.0000092960GASEOSO-1301067OXIDO DE ETILENO(l)C2H4O373.15nd21.039-0.086410.000172280LIQUIDOnd68OXIDO DE HIERRO (hematita)Fe2O3960-82420011.8120.0096970-197600SOLIDO-74220069OXIDO DE HIERRO (magnetita)FE3O4850-11184009.5940.027112040900SOLIDO-101540070OXIDO NITRICONO2000902503.3870.00062901400GASEOSO8655071OXIDO NITROSON2O2000820505.3280.0012140-92800GASEOSO10420072OXIGENOO2200003.6390.0005060-22700GASEOSOnd73PROPANOC3H81500-1046801.2130.028785-0.0000088240GASEOSO2429074PROPILENOC3H61500197101.6370.022706-0.0000069150GASEOSO6220575SODIONa37101.9880.00468800SOLIDOnd76SULFURO DE HIDROGENOH2S2300-206303.9310.0014900-23200GASEOSO-3356077SULFURO DE HIERRO (Pirita)FeS2411-1782002.6120.01328600SOLIDO-16690078TETRACLORURO DE CARBONOCCl4373.15nd21.155-0.048280.000101140LIQUIDOnd79TETRAOXIDO DE DINITROGENON2O42000916011.6600.0022570-278700GASEOSOnd80TOLUENO(g)C7H81500501700.2900.047052-0.0000157160GASEOSO12205081TOLUENO(l)C7H8373.151218015.1330.006790.000016350LIQUIDO11363082TRIOXIDO DE AZUFRE(g)SO32000-3957208.0600.0010560-202800GASEOSO-37106083TRIOXIDO DE AZUFRE(l)SO3373.15-441040-2.930.13708-0.000084730LIQUIDOnd84YODOI2386.806.4810.00150200SOLIDOnd

85ACIDO ACETICOC2H4O2298-484500LIQUIDO-389900861,2-ETANODIOLC2H6O2298-454800LIQUIDO-32308087METILCICLOHEXANOC7H14298-154770GASEOSO27480METILCICLOHEXANOC7H14-190160LIQUIDO20560AMONIACONH3298ndACUOSO-26500CLORURO DE CALCIOCACL2298ndACUOSO-8101900CLORURO DE CALCIOCACL2.6H2O298-2607900SOLIDOnd