Equilibrio Liquido Vapor Etanol-Agua Uniquac, Wilson NTRL

7/25/2019 Equilibrio Liquido Vapor Etanol-Agua Uniquac, Wilson NTRL

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ETANOL

COMPONENTES A B C x1

agua 18.3036 3816.44 -46.13 0.0303

etanol 18.9119 3803.98 -41.66 0.0606

n propanol 17.5439 3166.38 -80.15 0.0909

0.1212

A12 A21 0.1515

-117.3381 425.7681 0.18180.2121

0.2424

0.2727

Diagonal 0.3030

0 1 0.3333

1 0 0.3636

0.3939

0.4242

0.4545

0.4848

0.5151

CONSTANTES DE ANTONE! SEOBTENEN DEL DATA BAN"#


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0.5454

0.5757

0.6000

0.6363

0.6666

0.6969

0.7272

0.7575

0.7878

0.8181

Mol$%&l$ '1 (1

ETANOL 1.8701 1.724

AGUA 3.0198 2.9160

N-!TOANOL 2.42 1.3

l1 l2

-0.1396 -1.5008


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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.90.0000

0.1000

0.2000

0.3000

0.4000

0.5000

0.6000

0.7000

0.8000

0.9000

1.0000

SISTEMA ETANOL,AGUA Y N-PROP

ETANOL

AGUA


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A)*A

x2 x3 + ln(1) ln(2) ln(3) 1

0.21 0.7597 8.3140 -0.4287397039 0.23579919 0.69069944 0.6513294456

0.2200 0.7194 8.3140 -0.3802362819 0.24878727 0.34838778 0.6836998442

0.23 0.6791 8.3140 -0.3292861274 0.26214425 0.71548538 0.7194371366

0.2400 0.6388 8.3140 -0.275735322 0.27591264 0.96160303 0.7590137984

0.25 0.5985 8.3140 -0.2193376328 0.29014273 0.13965956 0.8030505362

0.2600 0.5582 8.3140 -0.1598138157 0.30489437 0.27300228 0.85230245960.27 0.5179 8.3140 -0.0968459197 0.3202393 0.37386209 0.9076958534

0.2800 0.4776 8.3140 -0.0300703802 0.33626423 0.44931049 0.9703772358

0.29 0.4373 8.3140 0.0409304128 0.35307492 0.5036675 1.0417796085

0.3000 0.3970 8.3140 0.1166384882 0.3708017 0.53962397 1.1237131207

0.31 0.3567 8.3140 0.1976131732 0.389607 0.55881656 1.2184909577

0.3020 0.3344 8.3140 0.2386730969 0.38198346 0.56277725 1.2695634445

0.281 0.3251 8.3140 0.2477258612 0.35544974 0.56054357 1.2811086825

0.2750 0.3008 8.3140 0.2948985022 0.35200919 0.5509421 1.3429900413

0.262 0.2835 8.3140 0.324679869 0.33880522 0.53757873 1.3835876457

0.2430 0.2722 8.3140 0.3384787919 0.31749296 0.52349032 1.4028119976

0.23 0.2549 8.3140 0.3684116612 0.30580162 0.50341453 1.4454369468


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0.2150 0.2396 8.3140 0.3929743509 0.29201942 0.48187624 1.4813803928

0.21 0.2143 8.3140 0.4463152224 0.29379899 0.44872271 1.5625439378

0.1950 0.2050 8.3140 0.4576009927 0.27957099 0.43052538 1.5802783347

0.17 0.1937 8.3140 0.466021655 0.25200063 0.40530213 1.5936415093

0.1600 0.1734 8.3140 0.5053712625 0.24714684 0.37030428 1.6576008112

0.13 0.1731 8.3140 0.4848068441 0.21419693 0.36000264 1.6238613201

0.1000 0.1728 8.3140 0.4645860991 0.18234343 0.35014888 1.5913553891

0.09 0.1525 8.3140 0.502450505 0.17886664 0.31377648 1.6527664248

0.0800 0.1322 8.3140 0.5408641969 0.17597716 0.27541654 1.717490471

0.07 0.1119 8.3140 0.5798313923 0.17368829 0.2351871 1.7857373163

0.0241040851

0.0495797705

0.0765475573

0.1051424881

0.1355164081, 0.1678406631

10 0.2023093328

0.2391431317

0.2785941394

0.3209515781

0.3665489149

0.402398268

0.4286810524

0.4661918529

0.4981967808

0.52448057170.5558388696

0.5850040248

0.6245746224

0.6444476225

0.6704367077

0.7042024051

0.7137309091

0.7226947378

0.7546670225

0.7867976902

0.8190879205

1


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1

NOL

Column G

Column B


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2 3 P!--g# T P/1 /2 /3

1.26592007 1.99511051 760.04 3.521E"02 5.20E"02 7.79E"02 3.65E"02

1.28246918 1.41678154 760.04 3.530E"02 3.53E"02 8.08E"02 3.80E"02

1.29971402 2.04517914 760.04 3.538E"02 3.65E"02 8.34E"02 3.93E"02

1.31773274 2.61588645 760.04 3.547E"02 3.78E"02 8.62E"02 4.07E"02

1.33661824 1.14988227 760.04 3.555E"02 3.91E"02 8.91E"02 4.22E"02

1.35648171 1.31390324 760.04 3.564E"02 4.05E"02 9.21E"02 4.38E"021.37745735 1.45333671 760.04 3.573E"02 4.19E"02 9.52E"02 4.54E"02

1.39970883 1.56723119 760.04 3.581E"02 4.33E"02 9.85E"02 4.70E"02

1.42343778 1.65477906 760.04 3.590E"02 4.48E"02 1.02E"03 4.87E"02

1.44889573 1.71536171 760.04 3.598E"02 4.62E"02 1.05E"03 5.03E"02

1.47640046 1.74860191 760.04 3.605E"02 4.75E"02 1.08E"03 5.18E"02

1.46518785 1.75554131 760.04 3.611E"02 4.87E"02 1.10E"03 5.31E"02

1.42682221 1.75162437 760.04 3.615E"02 4.95E"02 1.12E"03 5.40E"02

1.42192159 1.73488668 760.04 3.617E"02 4.98E"02 1.13E"03 5.44E"02

1.40326999 1.71185696 760.04 3.616E"02 4.95E"02 1.12E"03 5.41E"02

1.37367957 1.68790872 760.04 3.610E"02 4.84E"02 1.10E"03 5.28E"02

1.35771294 1.6543605 760.04 3.598E"02 4.63E"02 1.05E"03 5.04E"02

SSTEMASOBA+CO


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1.33912902 1.6191094 760.04 3.580E"02 4.31E"02 9.79E"02 4.68E"02

1.34151422 1.56631027 760.04 3.554E"02 3.88E"02 8.85E"02 4.19E"02

1.3225623 1.53806537 760.04 3.534E"02 3.58E"02 8.19E"02 3.85E"02

1.28659685 1.49975556 760.04 3.603E"02 4.72E"02 1.07E"03 5.14E"02

1.28036711 1.4481752 760.04 3.604E"02 4 .73E"02 1.07E"03 5.15E"02

1.2388666 1.4333332 760.04 3.602E"02 4.70E"02 1.06E"03 5.12E"02

1.20002624 1.41927883 760.04 3.601E"02 4.67E"02 1.06E"03 5.09E"02

1.19586125 1.3685838 760.04 3.595E"02 4.56E"02 1.03E"03 4.96E"02

1.19241082 1.31707918 760.04 3.588E"02 4.44E"02 1.01E"03 4.83E"02

1.18968467 1.26514545 760.04 3.580E"02 4.31E"02 9.79E"02 4.68E"02

0.97589591 0.0230371263 0.9769628737 1.04089703 0.8646391538

0.95042023 0.0474399576 0.9525600424 1.04078831 0.8649669198

0.92345244 0.0733336478 0.9266663522 1.04069285 0.8652548665

0.89485751 0.1008591248 0.8991408752 1.04059512 0.8655497472

0.86448359 0.1301756568 0.8698243432 1.04049559 0.86585021660.83215934 0.1614639357 0.8385360643 1.04039492 0.866154282

0.79769067 0.1949298049 0.8050701951 1.04029404 0.8664590712

0.76085687 0.2308087931 0.7691912069 1.04019432 0.8667605247

0.72140586 0.2693716662 0.7306283338 1.04009761 0.867052989

0.67904842 0.3109312724 0.6890687276 1.04000649 0.8673286911

0.63345109 0.3558510488 0.6441489512 1.03992442 0.8675770755

0.59760173 0.3913004396 0.6086995604 1.03985607 0.8677840034

0.57131895 0.4173646061 0.5826353939 1.03980766 0.8679306317

0.53380815 0.454673234 0.545326766 1.03978687 0.8679936

0.50180322 0.4866082407 0.5133917593 1.03980386 0.8679421392

0.47551943 0.5129055586 0.4870944414 1.03987058 0.86774006750.44416113 0.5443640515 0.4556359485 1.04000096 0.8673454114

0.41499598 0.5737048117 0.4262951883 1.04021019 0.8667125526

0.37542538 0.6136412536 0.3863587464 1.04051377 0.8657953434

0.35555238 0.6337536301 0.3662463699 1.04074966 0.8650834853

0.32956329 0.6601121283 0.3398878717 1.03994487 0.8675151765

0.29579759 0.694453549 0.305546451 1.03994074 0.8675276878

0.28626909 0.7041641641 0.2958358359 1.03995824 0.8674747098

0.27730526 0.7133072247 0.2866927753 1.03997553 0.8674223666

0.24533298 0.7459814237 0.2540185763 1.04004365 0.8672162284

0.21320231 0.7789163774 0.2210836226 1.04012196 0.8669793417

0.18091208 0.8121152196 0.1878847804 1.04021019 0.8667125526

2 1 2 12 21


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1 2 3 S*MA

0.01350238 0.9862150953 0.0002825275 0.9997174725

0.01927032 0.9809873405 1.268E"01 1.0002576562

0.03143092 0.9687824687 1.890E"01 1.0002133851

0.04572253 0.9544527609 2.498E"01 1.0001752887

0.0625708 0.937572146 1.135E"01 1.0001429436

0.08249042 0.9176254594 1.342E"01 1.00011588380.10610019 0.8939934216 1.535E"01 1.0000936134

0.1341366 0.8659390278 1.711E"01 1.0000756233

0.16746203 0.8325993792 1.866E"01 1.000061412

0.20706032 0.7929901879 1.994E"01 1.0000505116

0.25400755 0.7460349688 2.089E"01 1.0000425205

0.29553895 0.7099772847 2.145E"01 1.0055162331

0.32846896 0.6830229269 2.175E"01 1.0114918878

0.37346563 0.6341490613 2.169E"01 1.0076146884

0.40985171 0.5865285005 2.128E"01 0.9963802069

0.433256 0.5392264777 2.053E"01 0.9724824826

0.45363906 0.4779840322 1.927E"01 0.9316230934


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0.45824258 0.4134356203 1.759E"01 0.8716782005

0.4597651 0.3349092732 1.537E"01 0.7946743697

0.44689529 0.2920139145 1.394E"01 0.7389092067

0.62980295 0.3506560592 1.779E"01 0.9804590054

0.6872445 0.3128150773 1.721E"01 1.0000595751

0.699658 0.3004047242 1.693E"01 1.0000627241

0.71124383 0.2888221191 1.667E"01 1.0000659537

0.75174399 0.2483359379 1.571E"01 1.0000799272

0.79094381 0.2091549856 1.473E"01 1.0000987943

0.82858617 0.1715381045 1.374E"01 1.0001242794


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A # $ A12 A21 A31

agua 18.3036 3816.44 -46.13 975.49 276.76 1128.2

etanol 18.9119 3803.98 -41.66 A13 A23 A32

n propanol 17.5439 3166.38 -80.15 1338.8 102.671 -40.8745

ag&a $anool n 'oanol

%1 %2 %3 LN &1 ln'2 ln'3 &1

0.09 0.56 0.3500 3.09984731 1.86800931 2.34378908 22.19

0.11 0.54 0.3500 3.68692559 1.72039727 1.94845781 39.921922

0.19 0.48 0.3300 2.12259152 1.29471962 2.91231317 8.352756

0.3 0.45 0.2500 0.86967542 0.85698327 2.0342806 2.386136

0.4 0.39 0.2100 0.36177156 2.43958695 1.31580329 1.435871

0.5 0.35 0.1500 0.13863471 1.97240824 1.58968831 1.148704

0.6 0.3 0.1000 0.08131559 2.36012778 2.69415857 1.084713

0.8 0.19 0.0100 0.44883083 3.58298626 2.82322453 1.566480

CONSTANTES DE ANTONE!SEOBTENEN DEL DATA BAN"#

PA+AMET+OS DELSON!OBTENDO DE TABLA DE

P+A*NT#

DATOS DE E*LB+O L*DO

APO+!TOMADO DE LO+A1992#

0.9

1

SINTEMA ETANOL, AGUA, N!"O!ANOL


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0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0

0.10.2

0.3

0.4

0.5

0.6

0.7

0.8

C

C

ETANOL

AGUA


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agua

Y2 Y3 P T p(p1 p(p2 p(p3 &1

6.47539 10.4206465 760 313.770482 57.0554287 138.706151 54.0754052 0.05401477

5.58675 7.01785638 760 318.140754 71.7455132 173.006526 69.3568903 0.02918771

3.64997 18.3993101 760 318.435131 72.8420231 175.55684 70.5062954 0.23733151

2.35604 7.64674907 760 337.43636 181.722093 424.494569 188.117739 0.52581368

11.46830 3.72774423 760 345.942262 263.530038 608.146289 278.916408 0.80339304

7.18797 4.90222072 760 354.060322 368.616654 841.579128 397.019406 0.89742953

10.59230 14.7930662 760 358.208775 434.635677 987.185293 471.751056 0.96721841

35.98083 16.8310354 760 355.471437 390.057393 888.944317 421.252997 0.99506239

0 1

1 0

SISTEMA

ISOBARICO


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lumn C

lumn L


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etanol n-propanol

&2 &3 )u*a

0.47384878 0.47204912 0.99991267

0.42460571 0.5464967 1.00029013

0.56930826 0.19332949 0.99996926

0.3419565 0.13208303 0.9998532

0.04249824 0.15350153 0.99939282

0.04397245 0.05857338 0.99997535

0.02180448 0.01089037 0.99991326

0.00451462 0.00107191 1.00064893


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SISTEMA ETANOL -AGUA -N PROPANOL

Componentes ANTA ANTB ANTC1 ethanol 18.9119 3803.98 -41.68

2 water 18.3036 3816.44 -46.13

3 n propanol 17.5439 3166.38 -80.15

Parametos de interaccion del chemcad

i Bi Bi ALP!A "#

1 2 -55.1581 670.441 0.3031

1 3 -1.28794 28.3007 0.3007

2 3 1005.23 223.596 0.485

R Presion T $%& '" '( ') T"( T("

1.987 760 346.79748483 0 0.56 0.44 -0.080045236 0.9729415689

1.987 760 352.73058996 0.09 0.51 0.4 -0.078698835 0.9565762046

1.987 760 356.89599504 0.18 0.46 0.36 -0.077780325 0.9454118109

CONSTANTS ! ANTO"N#!ATOSTO$A!OS ! !ATA %AN&'

SISTEMA

ISOBARICO


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1.987 760 356.13459891 0.27 0.41 0.32 -0.077946616 0.9474330492

1.987 760 354.59502761 0.36 0.36 0.28 -0.078285042 0.9515465889

1.987 760 352.07591118 0.45 0.31 0.24 -0.078845175 0.9583549407

1.987 760 349.2136532 0.54 0.26 0.2 -0.079491413 0.9662099001

1.987 760 346.23318353 0.63 0.21 0.16 -0.080175697 0.9745272984

1.987 760 343.18183536 0.72 0.16 0.12 -0.080888566 0.9831921571

1.987 760 339.5426185 0.81 0.11 0.08 -0.08175553 0.9937300079

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1

Column AM

Column E

fraccion olar !"anol

fraccion olar a#$a


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T") T)" T() T)( G"( G(" G") G)"

-0.001869054 0.0410698741 1.4587861621 0.3244817114 1.0245584212 0.7446070946 1.0005621825 0.9877262336

-0.001837615 0.0403790583 1.4342486485 0.3190237665 1.0241403902 0.7483097761 1.0005527237 0.9879314336

-0.001816168 0.0399077861 1.4175092434 0.3153003758 1.0238553088 0.7508462915 1.000546271 0.9880714448


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-0.001820051 0.0399931068 1.4205398 0.3159744706 1.023906915 0.7503864359 1.0005474392 0.9880460953

-0.001827953 0.0401667478 1.4267074621 0.3173463602 1.0240119498 0.7494514267 1.0005498167 0.9879945069

-0.001841032 0.0404541424 1.4369156078 0.3196169854 1.0241858173 0.7479064449 1.0005537517 0.9879091286

-0.001856122 0.0407857164 1.4486929915 0.3222366604 1.0243864492 0.7461279187 1.0005582917 0.9878106347

-0.0018721 0.041136811 1.4611637358 0.3250105614 1.0245989355 0.7442492966 1.000563099 0.9877063529

-0.001888746 0.0415025726 1.474155447 0.3279003425 1.0248203454 0.7422972253 1.0005681071 0.9875977265

-0.001908989 0.0419473971 1.4899554411 0.3314147775 1.0250896796 0.7399300936 1.0005741978 0.9874656355


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G() G)( *"

0.4928692818 0.8543847754 0.4973652956 -0.401718423 -2.261342323 0.1146701594 0.3244817114 0

0.4987698089 0.8566494161 0.4904960518 -0.26814431 -1.183390754 0.3824952625 0.234717399 0.0404081919

0.5028356092 0.8581977894 0.4859976735 -0.179949858 -0.662137891 0.7004095277 0.1684314287 0.0885627354


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0.5020970742 0.8579172595 0.4875190813 -0.121443015 -0.385628137 0.9806378317 0.1183271092 0.1493677581

0.5005973873 0.85734662 0.4901560111 -0.080639648 -0.225190022 1.2024081542 0.0777423889 0.2278093028

0.4981250795 0.856402984 0.4942692276 -0.052127969 -0.129120004 1.3675505981 0.0440481402 0.3330674556

0.4952878844 0.8553155787 0.4992803758 -0.032236638 -0.070746035 1.4863117317 0.0153965168 0.4804687921

0.4923012703 0.8541656604 0.5052476 -0.01859405 -0.035592837 1.5699765973 -0.00937801 0.7000213974

0.4892090421 0.8529693483 0.5128550185 -0.009566546 -0.015223564 1.6291605943 -0.031089964 1.059399551

0.4854745616 0.8515166996 0.524945075 -0.003993181 -0.004481694 1.6761008952 -0.050428353 1.7517545545


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*( *) P+p" P+p(

0 1.3833135045 1.4587861621 0 0 4.3007359624 629.31804706 273.2467182

0.2174906141 1.6365922847 1.0587817169 -0.051520445 0.0704267988 2.9378795247 798.26642231 349.32576256

0.2733920574 1.6995885995 0.7961761091 -0.113163495 0.1026305903 2.1938175596 938.27954275 412.7525953


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0.2724713308 1.7162920829 0.6133102736 -0.19137744 0.1144845291 1.7098700316 911.25954457 400.48882381

0.246960374 1.7376125369 0.4745551053 -0.292897675 0.1138503589 1.3438085569 858.60504086 376.62168523

0.2118146582 1.8020596379 0.3655854744 -0.43021213 0.1057551882 1.041986026 777.93918956 340.14394669

0.1734223091 1.9528456529 0.2773261427 -0.62460943 0.0929804501 0.7754569295 694.07987473 302.34383551

0.1349301144 2.2831898033 0.2042688114 -0.918778084 0.0773131171 0.5287729446 614.94718917 266.80213467

0.0978601584 3.0838220278 0.1427683225 -1.412532735 0.0599225967 0.2982444534 541.92505431 234.12987459

0.0629254125 5.8372022428 0.0903144867 -2.408662513 0.0416282105 0.1026202687 464.50805454 199.64180338


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+,agonal

P+p) ," ,( ,) ' ,

289.77965523 0 0.2785159081 0.7215222962 1.0000382044 0 1

375.24994425 0.03615787 0.3836433716 0.5802311199 1.0000323616 0.1 0.9

446.94413677 0.1556478785 0.424597919 0.4644539505 1.044699748 0.2 0.8


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433.05662293 0.3174686943 0.3708103645 0.3117770701 1.0000561289 0.3 0.7

406.06267175 0.4890285958 0.3099896346 0.2010364974 1.0000547278 0.4 0.6

364.90072449 0.6299237392 0.2500230263 0.1200699334 1.0000166989 0.5 0.5

322.3878476 0.7329924904 0.2019894995 0.0657889185 1.0007709085 0.6 0.4

282.57306273 0.8003094713 0.1683205024 0.0314562085 1.0000861822 0.7 0.3

246.13729359 0.8364154202 0.1520031294 0.0115909078 1.0000094574 0.8 0.2

207.88791299 0.8297835743 0.1686690185 0.002245633 1.0006982258 0.9 0.1

1 0

Equilibrio Liquido Vapor Etanol-Agua Uniquac, Wilson NTRL

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