Reactores Químicos I (1). (3)

7/25/2019 Reactores Qumicos I (1). (3)

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Hoja de Clculo para el Clculo d

Reaccin Qumica:

No. Comp i i (mol) n,i Hf,i, (J/mol)1 -1 2 0

2 CO -1 3 -39309

3 HO 1 0 -2!1"1"

! CO 1 0 -1102

#

$

"

0

29" %

&' ".31! J/mol % !todo

' 1000 %

n %'

Comp i *i ni %'

0.1"1$92#" 0.90"9#339#

CO 0.3"1$92#" 1.90"9#339#

HO 0.21"20$32 1.09103##0!! n +on &..'

CO 0.21"20$32 1.09103##0!! f &..'

1 Conin'

n

"r#co K $s. % "r#co &n

% K ('%) '*+,

H () CO () 4 HO () CO ()

H

n

'

n %'

H


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300 1.0$"5-00 33.3333333333

32 3."220$5-00 30.$#9230$#92

30 0.0001129#! 2".$1!2"$1!

3$ 0.0002"$932! 2#.#########$

!00 0.000#0#921 2

!2 0.0013310!$ 23.29!11$#!$

!0 0.0020"1""2 22.2222222222!$ 0.00!!0##23 21.02#31$"9

00 0.00$29#"!03 20

2 0.011!"2$9" 19.0!$#190!$#

0 0.01$30!2939 1".1"1"1"1"1"

$ 0.0210011$1 1$.39130!3!$"

#00 0.03220!91$ 1#.#########$

#2 0.0!"002932 1#

#0 0.0#3$#!3!"$ 1.3"!#13"!#

#$ 0.0"2$92!$!$ 1!."1!"1!"1!"

$00 0.103393131 1!.2"$1!2"$$2 0.131#1##0"" 13.$93103!!"3

$0 0.1#1$9322!$ 13.3333333333

$$ 0.1999!20"! 12.90322"0#

"00 0.23!3012"3 12.

"2 0.2$#$!001 12.1212121212

"0 0.3233!$3#9 11.$#!$0""2!

"$ 0.3$!0##"#1 11.!2"$1!2"#

900 0.!2""2329!3 11.1111111111

92 0.!"$2$$09 10."10"10"10"

90 0.00912!# 10.2#31$"9

9$ 0.#1#2$2#! 10.2#!102#!

1000 0.#"#01##3#2 10

102 0.$9109$$1 9.$#09$#1

100 0."33$0!## 9.23"0923"

10$ 0.91!#0#$0"$ 9.30232"1!

1100 0.99##2130" 9.0909090909

112 1.0"121!22" "."""""""""9

110 1.1#"1"!##3 ".#9#21$39

11$ 1.2$332"0! ".10#3"29$9

1200 1.3!"!#13 ".3333333333

122 1.!!13$#"3"1 ".1#32#30#1

120 1.3"90#!33 "

12$ 1.#31"19903! $."!313$2!9

1300 1.$2"9""1"09 $.#9230$#923

132 1."2$22#0002 $.!$1#9"113

130 1.92#3$12399 $.!0$!0$!0$!

13$ 2.02#2#9!03" $.2$2$2$2$2$

1!00 2.12#$$3$"#9 $.1!2"$1!29


3/62

1!2 2.22$$!0" $.01$!3"9#

1!0 2.32903$23 #."9#1$2!1

1!$ 2.!30$133 #.$$9##101#9

100 2.3219!2913 #.#########$

12 2.#33"0322$ #.$3$$0!92

10 2.$33012923 #.!1#129032

1$ 2."3#9!93!$ #.3!920#3!921#00 2.93$9$!03 #.2

1#2 3.03"22"$20$ #.13"!#13"

1#0 3.13"!1!9392 #.0#0#0#0#0#

1#$ 3.23"0""329 .9$01!923$

1$00 3.33$1"#"#1 .""2329!12

1$2 3.!3#39##! .$9$101!!93

1$0 3.33!3"232 .$1!2"$1!3

1$$ 3.#30!9323 .#33"02"1#9

1"00 3.$2#$$$0302 .#

1"2 3."22221!3 .!$9!20!"1"0 3.91#""1##3 .!0!0!0!

1"$ !.010#!#32" .3333333333

1900 !.103102921 .2#31$"9!$

192 !.19!3"#$ .19!"019!"

190 !.2"#!$"3#1 .12"2012"2

19$ !.3$#0$1$3 .0#32911392

2000 !.!#"3$$0$


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e la Constante de Equilibrio (K).

6f,i, (J/mol)i Hf,i, (J) i 6f,i, (J) 7i 8i0 0 0 3.2!9 !.225-0!

-39!39 39309 39!39 .!$ 1.05-03

-22"$2 -2!1"1" -22"$2 3.!$ 1.!5-03

-13$1#9 -1102 -13$1#9 3.3$# .$5-0!

0 0

0 0

0 0

0 0

!11## 2"#1"

H 6

corto: !todo Ri-uroso:

-11.0"2!$9 J' !""22.!203# J

0.11322"9#! ' 1".01#"#3 mol

1.119""$90# H' 3!#3.!10$# J

n %' -0.3$#"3!

1.09103##0!!

0.!1"3022 %' 0.#"#01##3#2

!.1"3021"

6' 3133.191$1"J

:' 31.0221"!J/%

$s. ('%)

&n K


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-11.!!00#3"12

-10.1$2132!0

-9.0""0"#013

-".12$"!#$#1

-$.33$!$39#"

-#.#21!!#011

-.9""19!#03-.!2!#!#2"!

-!.920313"#!

-!.!###"90$9

-!.0#"00#03

-3.#"!""2$#"2

-3.3!#12$21!"

-3.03#!931$$1

-2.$2#10!2

-2.!91!1"10$

-2.20#""3-2.02$"#20#12

-1."21!3#1!9#

-1.#29#$01#9

-1.!11!$!!"

-1.2"!#2!!!#"

-1.12900301$

-0.9"3320$139

-0."!#$103!#!

-0.$1"!0"0#2

-0.9$$290$3

-0.!"!0#1$2

-0.3$#"3!00

-0.2$#0"""#2

-0.1$9"$99"01

-0.0"92#1132$

-0.0033"!!1!9

0.0$"0"!#92

0.1!09$$

0.22"992#1

0.29"9#!20"

0.3#9"$9!3

0.!29110!3#!

0.!"9#9"9$1

0.!$3#3$09

0.#02$9"9#99

0.##3"0!##

0.$0#19#3$02

0.$!#0#1$$!

200 !00 #00 "00 1000 1200 1!00 1#00 1"00

0

1

2

3

!

K

0 10 1 20 2 30 3

-1!

-12

-10

-"

-#

-!

-2

0

2

!&n K


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0."00990110!

0."!!#20$"

0."""12$909"

0.9290"#23$

0.9#"!2""9

1.00#2!191

1.0!2#0!3##21.0$$9203

1.1112$!#"$9

1.1!3$1$"$#

1.1$!9"31339

1.2012"191

1.23!20$290"

1.2#22$1!0#3

1.2"93#"11

1.31!3$932

1.3!0"39"1$1.3#29#$3$

1.3""92!"!

1.!11"!2$$#2

1.!3!0012#

1.!!#0$12#

1.!$#20#2!#

1.!9#3999!9


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Ci ;i i 7i i 8i i Ci i ;i0 ".30503 -3.2!9 -0.000!22 0 -"300

0 -1.1#50 -.!$ -0.0010! 0 11$00

0 1.2150! 3.!$ 0.001! 0 12100

0 -3.10503 3.3$# 0.000$ 0 -3100

0 0 0 0

0 0 0 0

0 0 0 0

0 0 0 0

-1."# 0.000! 0 11#!00

7 8 C ;

< m=>' 2


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000 2200

%

!0n %

900 90 1000 100 1100 110.

0.$

0.9

1.1

1.3

1.

% (K)

n i

(moles)

900 1000 1100

2

2.1

2.2

2.3

2.!

2.

2.#

2.$

2."

2.9

% (K)

n

(moles)

1000 1100

0.

0.$

0.9

1.1

1.3

1.

1.$

1.9

2.1

% (K)

n i

(moles)


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'


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Gi

Clculo de % por el !todo de /e7ton0Rap1son

5= p ( p) ?( p) n

0.2023091 0 -1.!290031" 0.03293"#9 93.3"3$23

0.02093""3 93.3"3$23 -0.10!923 0.02"213# 9$.11$$"!

0.0002192$ 9$.11$$"! -0.000##"3" 0.02$"9!!$ 9$.1!1$!2.!0395-00" 9$.1!1$! -2.$1"5-00" 0.02$"922 9$.1!1$!#

0 9$.1!1$!# 1.22125-01 0.02$"922 9$.1!1$!#

0 9$.1!1$!# 1.22125-01 0.02$"922 9$.1!1$!#

0 9$.1!1$!# 1.22125-01 0.02$"922 9$.1!1$!#

0 9$.1!1$!# 1.22125-01 0.02$"922 9$.1!1$!#


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5=

0.0$3112!2

0.00#23!"

!.012#5-001.#3205-009

0

0

0

0


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Hoja de Clculo para el Clculo de la Constante de Equilibrio (K).

Reaccin Qumica:

CHK () 4 CHI () H ()

No. Comp i i (mol) n,i Hf,i, (J/mol) 6f,i, (J/mol) i Hf,i, (J) i 6f,i, (J) 7i 8i

1 CHK -1 1 -"3"20 -31" "3"20 31" 1.131 1

2 CHI 1 0 210 #"!#0 210 #"!#0 1.!2! 1

3 H 1 0 0 0 0 0 3.2!9 !

! 0 0

0 0

# 0 0

$ 0 0

" 0 0

1 1 13#330 10031

H 6

!todo Ri-uroso:

J' 12932$.""9 J

29"%

&' ".31! J/mol % !todo corto: ' -$."$9"$91 mo

' "00 % -!0.!"923$0!3! H' 1!2$2"."!# JA' 20 =

n %' -.9#0#!!130# n %' -.2$"09#1

Comp i *i ni %' 0.002$"20$ %' 0.00113"1

CHK 0.9#"93# 0.9"!0!#3 6' 3090.!#!" J

CHI 0.01$031$ 0.0193$

H 0.01$031$ 0.0193$ n +on &..' 0.0193#9$ :' 13!.!$9$$ J/%

0 0 f &..' 0.0193#9$

n

'

n %'


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1 1.0193$ Conin' 1.93#9$!3 %p' 0.0002!9

A *i

10 0.9"30!9"1 0.0220"!$

"r#co &n K $s. ('%) 20 0.9#"93#23 0.01$031$ 0

('%) '*+, &n K 30 0.9$!3091222 0.012"!!! 0

0 -#$.21""10!9# !0 0.9$$$3#0"29 0.0111319# 0

!!.!!!!!!! -".231#0211! 0 0.9"00"!23!1 0.0099$"" 0

!0 -1.0132#222" #0 0.9"1"230#2 0.0090""!$ 0

"r#co K $s. % 3#.3#3#3#! -!.0"3231211# $0 0.9"31$"0!3 0.00"!109" 0

% K "0 0.9"!2$2$"$$ 0.00$"#3#1 0

200 #.!3!5-030 90 0.9"1"1!9# 0.00$!092$ 0

22 .132#5-02# 100 0.9"91#3 0.00$02!1" 0

20 $.00205-023 0

2$ 2.#3395-020

0 10 20 30 !0 0 #0 $0 "0 90 100

0

0.2

0.!

0.#

0."

1

6i34(5)

CHKCHI

H

5 (bar)

6 i

0 10 20 30 !0

0

0.0001

0.0002

0.0003

0.000!

0.000

0.000#

Kp34

5

Kp


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Ci ;i i 7i i 8i i Ci i ;i Gi A+i (=) +i (%) Ai (=) i (%)

-.#5-0# 0 -1.131 -0.01922 .#105-00# 0 1 !".$2 30.3 0.!100903 2.#20

-!.395-0# 0 1.!2! 0.01!39! -!.3925-00# 0 0.! 2"2.3 0.39#"2! 2."33

0 ".30503 3.2!9 0.000!22 0 "300 13.13 33.19 1.232292 2!.10

0 0 0 0

0 0 0 0

0 0 0 0

0 0 0 0

0 0 0 0

3.!2 -0.00!!09 1.1#905-00# "300

7 8 C ;

< m=>' 1


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%p

0.000102$

0.0002!9

0.0001#93#

0.00012#$!

0.0001011$

".!1305-00

$.195-00

#.2"2!5-00

.$235-00

.00!25-00

$0 "0 90 100


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8Li Mi n i i

0.1399113 0.1 0.0009$""" 1.0009$93#

0.13#"3!#1 0.0"$ 0.00212$"" 1.0021301!

0.13"999$3 -0.21# 0.0031"3"9 1.0031""9#


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51/62

Hoja de Clculo para el Clculo de la Constant

Reaccin Qumica:

CO () 2 H ()4 CHFOH ()

No. Comp i i (mol) n,i Hf,i, (J/mol) 6f,i, (J/mol)1 CO -1 1 -1102 -13$1#9

2 H -2 2 0 0

3 1 0 -200##0 -1#19#0

!

#

$

"

-2 3

29" %

&' ".31! J/mol % !todo corto:

' 300 % 10.00#1#$32"3

A' 100 =

n %' 9.$#3#31!90"

Comp i *i ni %' 1$3"9.##$##933

CO 0.023$22 0.02!90$0

H 0.0!$!0! 0.0!9"1!1

0.92""2!39 0.9$0929 =) n +on &..' 0.9$0929!"2

0 0 f &..' 0.9$0929!"2

1 1.0!9"1!1 Conin' 9$.0929!"1$

n


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de Equilibrio (K).

i Hf,i, (J) i 6f,i, (J) 7i 8i Ci ;i1102 13$1#9 3.3$# .$5-0! 0 -3.10503

0 0 3.2!9 !.225-0! 0 ".30503

-200##0 -1#19#0 2.211 1.225-02 -3.!5-0# 0

0 0

0 0

0 0

0 0

0 0

-9013 -2!$91

H 6

< m=>'

!todo Ri-uroso:

J' -$2#.!319 J

' 21.$99929mol

H' -9021#.2902 J

n %' 9.$#32229

%' 1$3"$.$#""

6' -2!32.1$$3 J

:' -219.!$0!3 J/%

Clculo de


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55/62

i 7i i 8i i Ci i ;i Gi A+i (=)-3.3$# -0.000$ 0 3100 1 3!.99

-#.!9" -0.000"!! 0 -1##00 1 13.13

2.211 0.01221# -0.000003! 0 "0.9$

0 0 0 0

0 0 0 0

0 0 0 0

0 0 0 0

0 0 0 0

-$.##3 0.010"1 -0.000003! -1300

7 8 C ;

1


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B)


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+i (%) Mi Ai (=) i +i Ai i +PQR Ai i Mi + Ai132.9 0.0!" 2."$99!2 -3$9."22"0$ -9!"901.22# -1".231!9!$

33.19 -0.21# $.#1#1!#23 -0.9$"$ -13$209.!"2 109.20091!

12.# 0.#! 1.230232 #33.0$39$" 13$119"1.$ 3$.03$2!

-22.30"#1 12#2"$1 !!".0231!3

S T U

Clculo de % por el !todo de /e7ton0Rap1son. )

p ( p) ?( p) n 5=

30 1.2!$1311#! -0.090!$2$ 3#3.$"!222 0.03$"912

3#3.$"!222 0.0!!03#9#2 -0.0"!201#9 3#!.30$21 0.001!3"

3#!.30$21 ."$9"35-00 -0.0"39$#99 3#!.30$91# 1.92195-00#3#!.30$91# 1.00935-010 -0.0"39$##9 3#!.30$91# 3.!325-012

3#!.30$91# 0 -0.0"39$##9 3#!.30$91# 0

3#!.30$91# 0 -0.0"39$##9 3#!.30$91# 0

3#!.30$91# 0 -0.0"39$##9 3#!.30$91# 0

3#!.30$91# 0 -0.0"39$##9 3#!.30$91# 0

Clculo de % por el !todo de /e7ton0Rap1son.

p ( p) ?( p) n 5=

30 10.!$!$12" -0.090!$2$ !#."3$$ 0.2!"2#

!#."3$$ 2.!!!3!01"#2 -0.0321"9 11.1#2$9 0.0"9$9#"11.1#2$9 0.202!#112# -0.0!!##00$ 1#.11202 0.00"90!!

1#.11202 0.001$00322 -0.0!392119 1#.10"! $.2115-00

1#.10"! 1.19#0"5-00$ -0.0!39103 1#.10"!3 .2$#"5-009

1#.10"!3 0 -0.0!39103 1#.10"!3 0

1#.10"!3 0 -0.0!39103 1#.10"!3 0

1#.10"!3 0 -0.0!39103 1#.10"!3 0


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Clculo de % por el !todo de /e7ton0Rap1son.

p ( p) ?( p) n 5=

!00 -$.$090$"909 0.0"19211 !9!.103231 0.190!2$

!9!.103231 -1.9$$9$1#1 0.01$$3"" 2!.9#!299 0.0"$"#9"

2!.9#!299 -0.09$1$2$9 0.0!#"1# 2$.091!$! 0.00!03#9

2$.091!$! -0.000!01"3! 0.0!30!#2 2$.1003!3 1.#"2$5-00

2$.1003!3 -#.92!5-009 0.0!3030# 2$.1003!! 2."99"5-0102$.1003!! 0 0.0!3030# 2$.1003!! 0

2$.1003!! 0 0.0!3030# 2$.1003!! 0

2$.1003!! 0 0.0!3030# 2$.1003!! 0


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i Mi +VQ Ai-1122#2!!$

2##9##!$".$

"."#25013

"."!$$5013

W


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r#co K $s. % "r#co &n K $s. ('%)

% K ('%) '*+, &n K

200 212!.2$#2 0 $.##11"#!!

22 103.3"3"# !!.!!!!!!! !.#3"!!#21

20 ".$01"#$1 !0 2.1#33$##

2$ 1.0911#1 3#.3#3#3#! 0.090"993

300 0.1"$019## 33.3333333 -1.#$#!1232 0.0!021!3 30.$#9230" -3.2092!31

30 0.010#1!!3 2".$1!2"# -!.!!0"

3$ 0.0032!3" 2#.######$ -.$3099!9

!00 0.00112"" 2 -#.$"91922#

!2 0.000!3!#9 23.29!11" -$.$!0""$12

!0 0.0001"3#$ 22.2222222 -".#023$!!3

!$ ".3"3#5-00 21.02#31# -9.3"##!9"

00 !.090$5-00 20 -10.10!2209

2 2.11!5-00 19.0!$#19 -10.$#3#""

0 1.1115-00 1".1"1"1"2 -11.3$21#9$$ #.2"5-00# 1$.39130!3 -11.93#12#

#00 3.""25-00# 1#.######$ -12.!9032

#2 2.3"!15-00# 1# -12.9!##929

#0 1.11$5-00# 1.3"!#1! -13.!022!!"

#$ 9."#$#5-00$ 1!."1!"1!" -13."2""3#

$00 #.#1215-00$ 1!.2"$1!3 -1!.22919$#

$2 !.3$5-00$ 13.$93103! -1!.#0$12

$0 3.1"2!5-00$ 13.3333333 -1!.9#0!$11

$$ 2.2$#"5-00$ 12.90322" -1.2931#3

"00 1.#905-00$ 12. -1.#11""

"2 1.22935-00$ 12.1212121 -1.911#13"

"0 9.2235-00" 11.$#!$09 -1#.19"13#

"$ $.0#!25-00" 11.!2"$1! -1#.!##!13

900 .!##05-00" 11.1111111 -1#.$221!1$

92 !.2"205-00" 10."10"10" -1#.9##2$$

90 3.393!5-00" 10.2#31" -1$.19""!3

9$ 2.$1"35-00" 10.2#!103 -1$.!20#$2

1000 2.1995-00" 10 -1$.#32!1"

102 1.$9#5-00" 9.$#09$# -1$."3!"2!$

100 1.!"0!5-00" 9.23"092 -1".02"3"0#

10$ 1.23005-00" 9.30232" -1".213##01

1100 1.03005-00" 9.09090909 -1".3911#

112 ".#"$95-009 "."""""""9 -1".#133"

110 $.3$915-009 ".#9#21$ -1".$2!#1#$

11$ #.30"!5-009 ".10#3"3 -1".""13"#9

1200 .!2#35-009 ".33333333 -19.032010"

122 !.#9!$5-009 ".1#32#31 -19.1$#"2!!

120 !.0"!25-009 " -19.31#1!03

12$ 3.$1#5-009 $."!313$2 -19.!02!9#

1300 3.13""5-009 $.#9230$#9 -19.$9!23$

132 2.$$1!5-009 $.!$1#9"1 -19.$0391#2130 2.!$95-009 $.!0$!0$!1 -19."239#!3

13$ 2.1"915-009 $.2$2$2$2$ -19.939$90!

1!00 1.9$5-009 $.1!2"$1! -20.01#02#

1!2 1.$$15-009 $.01$!3"# -20.199$

1!0 1."305-009 #."9#1$2 -20.2#39$3

1!$ 1.!3115-009 #.$$9##102 -20.3#!"$1

100 1.29"05-009 #.#######$ -20.!#2!9!

12 1.1"105-009 #.$3$$0 -20.#91"!

10 1.0$$"5-009 #.!1#129 -20.#!"3$9#

1$ 9."#3"5-010 #.3!920#3 -20.$3#9"01#00 9.0215-010 #.2 -20."22"12

1#2 ".32"95-010 #.13"!#1 -20.90#112


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1#0 $.#"2#5-010 #.0#0#0#0# -20.9"#""93

1#$ $.10335-010 .9$01!92 -21.0#2"!

1$00 #."2$5-010 .""2329! -21.1!1!0#

1$2 #.1135-010 .$9$101! -21.213!1

1$0 .#"95-010 .$1!2"$1 -21.2"$22!1

1$$ .305-010 .#33"02"2 -21.3$10#

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Reactores Químicos I (1). (3)

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Transcript of Reactores Químicos I (1). (3)