011abr
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MATERIAL SAFETY DATA SHEET
SECTION 1 -- PRODUCT AND COMPANY IDENTIFICATION
CUSTOMER: ABRO INDUSTRIES, INC.
PRODUCT NUMBER: SP-011
PRODUCT NAME: ABRO Spray Paint, Gloss Black
ISSUE DATE: Sept. 14, 2007
PREPARED BY: SKSMANUFACTURER: ABRO INDUSTRIES, INC.
3580 Blackthorn Court
South Bend, IN 46628
EMERGENCY TELEPHONE NUMBER: 800-424-9300 (24 Hours)* *for medical, spill, leak, fire or transport accident emergencies
SECTION 2 -- COMPOSITION/INFORMATION ON INGREDIENTS
% by WT
CAS No. INGREDIENT UNITS VAPOR PRESSURE
18 74-98-6 Propane ACGIH TLVOSHA PEL
2500ppm1000ppm
760 mm
17 106-97-8 Butane ACGIH TLVOSHA PEL
800ppm800ppm 760 mm
4 64742-89-8
Lt. AliphaticHydrocarbonSolvent ACGIH TLVOSHA PEL
100ppm100 ppm
53 mm
6 64742-89-8
V.M.&P. Naphtha ACGIH TLVOSHA PELOSHA PEL
300ppm300ppm400ppm STEL
12 mm
14 108-88-3 Toluene
ACGIH TLVOSHA PELOSHA PEL
20ppm
100ppm(Skin)150ppm(Skin)STEL
22 mm
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1 95-63-6 1,2,4-Trimethylbenzene ACGIH TLVOSHA PEL
25 ppm25 ppm
2.03 mm
29 67-64-1 Acetone ACGIH TLV ACGIH TLVOSHA PEL
500 ppm750 ppm STEL1000 ppm
180 mm
0.6 1333-86-4 Carbon Black ACGIH TLVOSHA PEL
3.5 mg/m33.5 mg/m3
SECTION 3 -- HAZARDS IDENTIFICATION
ROUTES OF EXPOSUREINHALATION of vapor or spray mist.EYE or SKIN contact with the product, vapor or spray mist.
EFFECTS OF OVEREXPOSUREEYES: Irritation.SKIN: Prolonged or repeated exposure may cause irritation.INHALATION: Irritation of the upper respiratory system.May cause nervous system depression. Extreme overexposure mayresult in unconsciousness and possibly death. Prolongedoverexposure to solvent ingredients in Section 2 may causeadverse effects to the liver, urinary, cardiovascular and
reproductive systems.SIGNS AND SYMPTOMS OF OVEREXPOSURE
Headache, dizziness, nausea, and loss of coordination areindications of excessive exposure to vapors or spray mists.Redness and itching or burning sensation may indicate eye orexcessive skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURENone generally recognized.
CANCER INFORMATIONFor complete discussion of toxicology data refer to Section 11.
SECTION 4 -- FIRST AID MEASURES
EYES: Flush eyes with large amounts of water for 15 minutes.Get medical attention.SKIN: Wash affected area thoroughly with soap and water.Remove contaminated clothing and launder before re-use.
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INHALATION: If affected, remove from exposure. Restore breathing.Keep warm and quiet.INGESTION: Do not induce vomiting. Get medical attentionimmediately.
SECTION 5 -- FIRE FIGHTING MEASURES
FLASH POINT LEL UELPropellant < 0 F 0.9 12.8
EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, FoamUNUSUAL FIRE AND EXPLOSION HAZARDSContainers may explode when exposed to extreme heat.
Application to hot surfaces requires special precautions.During emergency conditions overexposure to decompositionproducts may cause a health hazard. Symptoms may not beimmediately apparent. Obtain medical attention.SPECIAL FIRE FIGHTING PROCEDURESFull protective equipment including self-contained breathingapparatus should be used. Water spray may be ineffective. Ifwater is used, fog nozzles are preferable. Water may be used tocool closed containers to prevent pressure build-up and possibleauto ignition or explosion when exposed to extreme heat.
SECTION 6 -- ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDRemove all sources of ignition. Ventilate the area.Remove with inert absorbent.
SECTION 7 -- HANDLING AND STORAGE
STORAGE CATEGORY: Not AvailablePRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEKeep away from heat, sparks, and open flame. Vapors willaccumulate readily and may ignite explosively.During use and until all vapors are gone: Keep area ventilated -Do not smoke - Extinguish all flames, pilot lights, and heaters -Turn off stoves,electric tools and appliances, and any othersources of ignition. Consult NFPA Code. Use approved Bonding andGrounding procedures. Contents under pressure. Do not puncture,incinerate, or expose to temperature above 120F. Heat fromsunlight, radiators, stoves, hot water,and other heat sourcescould cause container to burst. Do not take internally. Keep outof the reach of children.
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SECTION 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION
PRECAUTIONS TO BE TAKEN IN USEUse only with adequate ventilation.
Avoid contact with skin and eyes. Avoid breathing vapor and spray
mist. Wash hands after using. This coating may contain materialsclassified as nuisance particulates (listed "as Dust" in Section2) which may be present at hazardous levels only during sandingor abrading of the dried film. If no specific dusts are listed inSection 2, the applicable limits for nuisance dusts are ACGIH TLV10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of oldpaint by sanding, scraping or other means may generate dust orfumes that contain lead. Exposure to lead dust or fumes may causebrain damage or other adverse health effects, especially inchildren or pregnant women. Controlling exposure to lead or otherhazardous substances requires the use of proper protectiveequipment, such as a properly fitted respirator (NIOSH approved)and proper containment and cleanup. For more information, callthe National Lead Information Center at 1-800-424-LEAD (in US) orcontact your local health authority.
VENTILATION
Local exhaust preferable. General exhaust acceptable if theexposure to materials in Section 2 is maintained below applicableexposure limits. Refer to OSHA Standards 1910.94, 1910.107,1910.108.
RESPIRATORY PROTECTIONIf personal exposure cannot be controlled below applicable limitsby ventilation, wear a properly fitted organic vapor/particulate
respirator approved by NIOSH/MSHA for protection againstmaterials in Section 2. When sanding or abrading the dried film,wear a dust/mist respiratorapproved by NIOSH/MSHA for dust which may be generated from thisproduct, underlying paint, or the abrasive.
PROTECTIVE GLOVESNone required for normal application of aerosol products whereminimal skin contact is expected. For long or repeated contact,wear chemical resistant gloves.
EYE PROTECTIONWear safety spectacles with unperforated sideshields.
OTHER PRECAUTIONS
Intentional misuse by deliberately concentrating and inhaling thecontents can be harmful or fatal.
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SECTION 9 -- PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT WEIGHT
SPECIFICGRAVITY
BOILINGPOINT
MELTINGPOINT
VOLATILE VOLUME
EVAPORATIONRATE
5.80lb/gal694 g/l
0.70
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TOXICOLOGY DATA
SECTION 12 -- ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATIONNo data available.
SECTION 13 -- DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD
CAS No. Ingredient Name
74-98-6 PropaneLC50 RAT 4HR Not AvailableLD50 RAT Not Available
106-97-8 ButaneLC50 RAT 4HR Not AvailableLD50 RAT Not Available
64742-89-8 Lt. Aliphatic HydrocarbonSolventLC50 RAT 4HR Not AvailableLD50 RAT Not Available
64742-89-8 V. M. & P. NaphthaLC50 RAT 4HR Not AvailableLD50 RAT Not Available
108-88-3 TolueneLC50 RAT 4HR 4000 ppmLD50 RAT 5000 mg/kg
95-63-6 1,2,4-TrimethylbenzeneLC50 RAT 4HR Not AvailableLD50 RAT Not Available
67-64-1 AcetoneLC50 RAT 4HR Not Available
LD50 RAT 5800 mg/kg
1333-86-4 Carbon BlackLC50 RAT 4HR Not AvailableLD50 RAT Not Available
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Waste from this product may be hazardous as defined under theResource Conservation and Recovery Act (RCRA) 40 CFR 261.
Waste must be tested for ignitability to determine the applicableEPA hazardous waste numbers. Do not incinerate. Depressurizecontainer. Dispose of in accordance with Federal,State/Provincial, and Local regulations regarding pollution.
SECTION 14 -- TRANSPORT INFORMATION
US Ground (DOT)May be classed as Consumer Commodity, ORM-DUN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)Canada (TDG) May be classed as Consumer Commodity, ORM-DUN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)IMO May be shipped as Limited Quantity UN1950, AEROSOLS, CLASS 2,LIMITED QUANTITY, EmS F-D, S-U Section 15 -- REGULATORYINFORMATION SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATIONCAS No. CHEMICAL/COMPOUND % by WT % Element 108-88-3 Toluene 1495-63-6 1,2,4-Trimethylbenzene 1CALIFORNIA PROPOSITION 65 WARNING: This product contains chemicals known to the State ofCalifornia to cause cancer and birth defects or otherreproductive harm.TSCA CERTIFICATION
All chemicals in this product are listed, or are exempt fromlisting, on the TSCA Inventory.
SECTION 16 -- OTHER INFORMATION
This product has been classified in accordance with the hazardcriteria of the Canadian Controlled Products Regulations (CPR)and the MSDS contains all of the information required by the CPR.The above information pertains to this product as currentlyformulated,and is based on the information available at thistime. Addition of reducers or other additives to this product maysubstantially alter the composition and hazards of the product.Since conditions of use are outside our control, we make nowarranties, express or implied, and assume no liability inconnection with any use of this information.