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1/12

CALCULOS Y RESULTADOS:

1. Tabla de datos donde se reporte tiempo y desplazamientos

HORA

Local

ALTURA DEL

MENISCO (cm) TIEMPO (s) Z-Zo (m)

tiempo

(ZZo) en

(s/m)7,! am 11,50 0 0

",#$am

11,40 3060 0,0210 145714,3

%,!!am

11,35 6120 0,0215 284651,2

%,!am

11,30 7200 0,0220 327272,7

#!,!!am

11,20 9720 0,0230 422608,7

#!,!am

11,15 10800 0,0235 459574,5

##,!!am

11,10 13320 0,0240 555000,0

##,!am

11,00 14400 0,0250 576000,0

#&,!!m''

10,90 16920 0,0260 650769,2

#&,!m

10,80 18000 0,0270 666666,7

#,!!m 10,70 20520 0,0280 732857,1

#,!m

10,60 21600 0,0290 744827,6

#*,!!m

10,50 24120 0,0300 804000,0

#*,!m

10,45 25200 0,0305 826229,5

#$,!!m

10,30 27720 0,0320 866250,0

#$,!m

10,20 28800 0,0330 872727,3

#+,!!m

10,10 31320 0,0340 921176,5

#+,!m

10,05 32400 0,0345 939130,4

#7,!!m

10,00 34920 0,0350 997714,3

#7,!m

9,95 36000 0,0355 1014084,5

Done Z#,$ cm .e es la al.0a el .1o en one se 0eal234 la0.e1a'


2/12

2. Grfca t/(Z-Zo) contra (Z-Zo).

0.0200 0.0250 0.0300 0.0350 0.0400

0.0

200000.0

400000.0

600000.0

800000.0

1000000.0

1200000.0

(x) = 49898743.96x - 729664.43R = 0.94

Z-Zo (!)

t/(Z-Zo) "n #"$%n&o#/!

'" $rfco #" ot*"n" +%" m=49,898,743.96 s /m2


3/12

3.

aa &" t"!"rat%ra#

o!o #" #a" +%"

El s2sema es A S.sanc2a eT0a1a5o (CICLOPENTANO)

6 A20e esancao

Ma 7!'#* /molM1 &",%7 /mol

R",#* (Pa-m)/(mol-8)T T9 0ome2o &7'** 9C

P0es24n # Am4s:e0a

O1se0;ac24n

Teme0a.0a 1.l1oseco (meo (


4/12

DENSIDAD DEL CICLOPENTANO L?@UIDO

orr"ac*n '"n#*t*"# o *nor$an*c an& or$an*c *+%* aa 2-30 "rr#an%a &" n$"n*"ro +%!*co (:t*!a ;&*c*n)

= 27.44


5/12

C4=1.96051017

C5=6

!*n.= 179.28

!ax.= 511.76

"!"rat%ra "n "?*n r"#*n "n a#ca"#

P vap=e[C1+C2T +C3ln (T)+C4TC5 ]

=46588.7832 a= 0.4597955 at!

ara a t"!"rat%ra &" 300.59 ara %na ?aor= 0.4597955 at!

@=0.4597955 at!, =1.00 at! arox*!a&a!"nt",

A= 1.00 at!-0.4597955 at!= 0.5402044 at!

PBML=1.00atm0.5402044 atm

ln

[

1.00atm

0.4597955 atm

]= 0.746655at!

@Bora &"#"Can&o ara "ncontrar a &*%#*?*&a&

DAB= RT PBMA , L

2mP(PA1PA2)MA

DAB=(8.206105

atmm3molK

)(1000moles

1Kmol )(300.59K)(0.746655 atm)(739.15

Kg

m3)

2(49,898,743.96s/m2)(1atm)(0.4597955 atm)(70.134 Kg

Kmol)

DAB=4.230052106

!2/#


6/12

EL ALOR O6TENIDO AL USAR LA CORRELACIBN DEILLILAND

ara " c*co"ntano a*r"

DAB=10

3T

1.75[ 1Ma+ 1Mb ]1 /2

P(( va)1/3+( vb)

1/3)2

vC5H10=5(14.8) D10(3.7)= 111 !o/c!3

vAire=

25.6 !o/c!3

- ?aor"# &" ?oE!"n"# !oar"# ot"n*&o# &" taa 2.3 &" *ro&" r"a "$%n&a ;&*c*n.

- >aor"# &" "#o !o"c%ar ot"n*&o &" taa 7.1 &" *ro &"r"a "$%n&a ;&*c*n.

DAB=

103(300.59)1.75

[

1

70.134 g/mol

+ 1

28,97g /mol ]

1 /2

1atm((111mol /cm3)1 /3+(25.6 mol/cm3)1 /3)2

El s2sema es A S.sanc2a eT0a1a5o (CICLOPENTANO)

6 A20e esancao

Ma 7!'#* /molM1 &",%7 /mol

R",#* (Pa-m)/(mol-8)T T9 0ome2o &7'** 9C

P0es24n # Am4s:e0a


7/12

DAB=0.079728 cm2/s=7.97277106

m2/s

El valor obtenido al usar la correlacin de Chap-

man-Enskog (Ref.2).

DAB=0.001858T

3 /2[ 1Ma+ 1Mb ]1/2

P(ab)2 D

;ncontran&o ?aor &" ar!"tro# (a*r")

Fa*r"/ = 97 aire=3.617Amstrog

ara c*co"ntano

c= 511.76

>c= 258 c!3/$!o ot"n*&o# &" @:n&*c" A !*tB >an "## +%*nta"&*c*Hn

Fc*co/ = 0.77(c) = 394.0551 ciclop=2.44 (!c )1 /3=5.182Amstrog

ab /K=394.055197=195.51

ab=5.182+3.617

2 =4.3995Amstrog

KT ab

=300.59K195.51

=1.5375

I""n&o " *nt"roan&o &" a taa .1 @Jn&*c" &" K"t #"$%n&a"&*c*n

D=1.1860


8/12

DAB=

0.001858(300.59)3/2[ 170.134 g/mol+ 128,97 g/mol ]1 /2

1atm (4.3995)21.1860

DAB=0.093159cm2

s =9.3158651106

3.1. ; ?aor cac%a&o a art*r &" a "c%ac*n (26-19, R".5), to!an&o &o#?aor"# &" o# ot"n*&o# "x-"r*!"nta!"nt".

o!o a ?aor &" c*co"ntano "# 0.4597955 at! &" ac%"r&o a a

" &" 'aton "i=Pi/Ptotal

"A1=0.4597955 atm

1atm =0.460

"B1=10.46=0.540

oa!"nt" "#t L%"n&o A %ro #or" a tra?:# &" a art" #%"r*or &"t%o or o tanto

"B2=1

"A2=0

;ntonc"# "A1"A2=0.46


9/12

"B, lm="B2"B1

ln [ "B2"B1]=

10.54

ln[ 10.54 ]=0.747

C= P

RT=

1atm

(8.206105atmm 3

molK )(

1000moles

1Kmol )(300.59K) = 0.040541

M!o/!3

*"!o= &" a# 730 a! a a# 530 ! #on 10 Bora#=36,000 #"$%n&o#

Ma=

739 ,15#g /m370.134 #g/#mol =10.5391#mol/m 3

Zo= 9.95 c! Z=11.5 c!

DAB=

Ma"B,lm

C t("A1"A2)(Z2Z o2)/2

DAB=

10.5391 #mol

m3

0.747

0.040541#mol

m 3 36,000 s (0.46) [

( [11.5102

m ]

2

[9.95102

m ]

2

)2 ]

DAB=1.9494105

m 2/s

3.2. Ntro ?aor "x"r*!"nta r"orta&o "n a A**o$raa, r""r"nc*ar.

o #" "ncontraron &ato# "x"r*!"nta"# &" #*#t"!a c*co"ntano-a*r"

4. r"#"ntar %na $rfca &" L%x contra t*"!o cac%ar " r"a aCo ac%r?a.

HORALocal

ALTURA DEL

TIEMPO

Z-Zo(m)

/(Z-Zo)en (s/m)

en2ene Da1 m&/s

Flux(mol/ m2-s)


10/12

MENISCO

(cm)(s)

7,!am

11,5 0 0 0 ! ! 0

9,00 a! 11,35 6120 0,0215 284651,2 277873800 7,59605;-07 0,000882039

9,30 a! 11,3 72000,02

2327272,7

852430002,47615;-

06 0,00280991110,00a!

11,2 97200,02

3422608,7

95336000 2,214;-06 0,00240319610,30a!

11,15 108000,0235

459574,573931600

2,85499;-06 0,003033025

12,00!.&.

10,9 169200,02

6650769,2

764778802,75994;-

06 0,00265011513,00

!10,7 20520

0,02

8732857,1

41043950

5,14264;-

06 0,0045852914,00!

10,5 24120 0,03 80400035571450

5,93381;-06 0,004938001

14,30!

10,45 252000,0305

826229,544459000

4,74762;-06 0,003886104

15,00!

10,3 277200,03

2866250

26680333,3

7,91123;-06 0,006172097

16,00!

10,1 313200,03

4921176,5

274632507,6857;-

06 0,0056434316,30!

10,05 324000,0345

939130,435907800

5,87823;-06 0,004253692

17,30!

9,95 36000 0,0355

1014084,532740400

6,44691;-06 0,004533793

Done Z#,$ cm .e es la al.0a el .1o en one se 0eal234 la 0.e1a'

;c%ac*n %t**Oa&a ara cc%o &" L%x

" "*!*naron o# &ato# +%" no #" acoaan con a t"n&"nc*a +%"r"#"ntaan o# &"!# &ato# ara +%" a c%r?a &" r"$r"#*n aar+%" "!aor nE!"ro &" %nto# "n a $rfca L%x contra t*"!o.


11/12

0 10000 20000 30000 400000

0

0

0

0

0.01

0.01

0.01

(x) = - 0xP2 D 0x - 0R = 0.83

Grfco L%x contra t*"!o

*"!o()

Q%x (!o/ !2-#)

Cati$a$ $e materia $i%&$i$a

0s

36000s

$'

Cati$a$$emateria$i%&$i$a=113.04mol /m2

5. R"ortar a cant*&a& &" #%#tanc*a &*%n&*&a "n !$.

'*!"tro &" a c"&a 3 !!

113.04mol /m2([ 3103m

2 ]2

= 0.000799!o"#


12/12

0.000799 moles70.134 g

1mol

1000mg

1g = 56.03936 !**$ra!o#

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