Masa Trabajo Fin
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Transcript of Masa Trabajo Fin
Sistema: Tetrahidrofurano (A) Agua(B) DIAGRAMA T-x,y a Presión constanteConstantes de Antoine A1 6.99515 8.07131
presión en mmHg y T en °C A2 1202.29 1730.63 Ingrese la Presión, mmHg, =A3 226.254 233.426
alfa= 3.0216
beta= 1.9436
B vBA
A vA B vB
A vAA A
P Px
P P
Py x
P
21
3
sat AlnP A
T A
DIAGRAMA P-x,y a Temperatura constante
Ingrese la Temperatura en °C =
DIAGRAMA T-x,y a Presión constante
Ingrese la Presión, mmHg, = 760 1 atmTsA= 65.9656634 puro
TsB= 99.9968297 puro
T °C PsA PsB xAsupuesto xA calculado yA99.9968 2041.63903 759.99919 2.9567E-06 4.73334044 1 9.0983274E-08 3.75959E-0599.4968 2015.22032 746.479324 0.00136459 4.71228071 1.00212048 0.00136459479 0.017050798.9968 1989.06381 733.160379 0.00275761 4.69088919 1.00428316 0.002757609 0.0338550398.4968 1963.16782 720.040019 0.00418011 4.66920387 1.00648951 0.00418010593 0.050416797.9968 1937.53067 707.115928 0.00563311 4.64721782 1.00874098 0.00563311353 0.0667384797.4968 1912.15067 694.385807 0.00711771 4.62492341 1.01103912 0.00711770481 0.0828234696.9968 1887.02616 681.847374 0.00863501 4.60231357 1.01338546 0.00863500998 0.0986741596.4968 1862.15546 669.498369 0.01018621 4.57938031 1.0157817 0.01018620912 0.1142935495.9968 1837.53689 657.336546 0.01177254 4.5561158 1.01822955 0.01177254341 0.129684395.4968 1813.16879 645.35968 0.01339531 4.53251168 1.02073083 0.01339531424 0.1448492894.9968 1789.04949 633.565561 0.01505589 4.50855942 1.02328744 0.01505588963 0.1597912594.4968 1765.17734 621.952 0.01675571 4.48425035 1.02590137 0.01675570876 0.1745128693.9968 1741.55067 610.516823 0.01849628 4.45957543 1.02857469 0.01849628539 0.1890168193.4968 1718.16783 599.257877 0.02027921 4.43452501 1.03130962 0.02027921226 0.2033059792.9968 1695.02717 588.173023 0.02210617 4.4090895 1.03410845 0.02210616974 0.2173829692.4968 1672.12704 577.260143 0.02397893 4.38325884 1.0369736 0.02397892945 0.2312504591.9968 1649.4658 566.517135 0.02589936 4.35702259 1.03990762 0.02589936148 0.2449111591.4968 1627.04179 555.941915 0.02786944 4.33036986 1.04291319 0.02786944149 0.2583677890.9968 1604.85339 545.532416 0.02989126 4.30328941 1.04599315 0.02989125899 0.27162390.4968 1582.89896 535.28659 0.03196703 4.27576962 1.04915046 0.0319670258 0.284679589.9968 1561.17687 525.202404 0.03409909 4.24779844 1.05238827 0.03409908545 0.2975398989.4968 1539.68548 515.277844 0.03628992 4.21936336 1.0557099 0.03628992343 0.3102068388.9968 1518.42318 505.510913 0.03854218 4.19045104 1.05911888 0.03854217865 0.3226831488.4968 1497.38835 495.899633 0.04085866 4.16104807 1.06261892 0.04085865639 0.3349713987.9968 1476.57937 486.442039 0.04324234 4.13114035 1.06621395 0.04324234156 0.3470742187.4968 1455.99462 477.136187 0.04569641 4.10071298 1.06990817 0.04569641462 0.3589943786.9968 1435.6325 467.980148 0.04822427 4.06975048 1.07370602 0.04822426855 0.3707346186.4968 1415.4914 458.972011 0.05082953 4.03823695 1.0776122 0.0508295269 0.3822975785.9968 1395.56972 450.109882 0.05351607 4.00615553 1.08163173 0.05351606587 0.3936859985.4968 1375.86586 441.391883 0.05628804 3.97348866 1.08576998 0.05628803717 0.4049026484.9968 1356.37823 432.816154 0.05914989 3.94021797 1.09003263 0.05914989422 0.4159502784.4968 1337.10524 424.38085 0.06210642 3.906324 1.09442582 0.06210642305 0.4268317983.9968 1318.04531 416.084145 0.06516277 3.87178659 1.09895606 0.0651627726 0.4375500183.4968 1299.19684 407.924228 0.06832449 3.83658447 1.10363034 0.06832449396 0.4481078282.9968 1280.55827 399.899305 0.07159758 3.80069515 1.10845618 0.07159758268 0.4585082382.4968 1262.12802 392.007598 0.07498852 3.76409509 1.11344164 0.0749885249 0.4687542281.9968 1243.90453 384.247347 0.07850435 3.72675927 1.11859543 0.07850435436 0.4788489381.4968 1225.88622 376.616806 0.08215271 3.68866132 1.12392693 0.08215271233 0.4887955580.9968 1208.07154 369.114248 0.08594192 3.6497733 1.12944628 0.08594191972 0.4985973980.4968 1190.45894 361.73796 0.08988106 3.61006556 1.13516447 0.08988105879 0.5082578679.9968 1173.04685 354.486247 0.09398007 3.56950651 1.14109343 0.09398006871 0.51778052
A B
79.4968 1155.83374 347.357428 0.09824985 3.52806256 1.14724615 0.098249854 0.527169178.9968 1138.81805 340.34984 0.10270242 3.48569751 1.15363683 0.10270241832 0.5364276178.4968 1121.99827 333.461834 0.107351 3.44237305 1.16028093 0.10735100236 0.5455601377.9968 1105.37284 326.69178 0.11221028 3.3980475 1.16719551 0.11221027776 0.5545711777.4968 1088.94024 320.038059 0.11729654 3.35267633 1.17439926 0.11729653985 0.5634654476.9968 1072.69895 313.499074 0.12262797 3.30621107 1.18191287 0.12262797164 0.5722481276.4968 1056.64744 307.073237 0.12822494 3.25859913 1.18975928 0.1282249383 0.5809248575.9968 1040.78421 300.758981 0.13411034 3.20978334 1.19796395 0.13411034399 0.5895017375.4968 1025.10774 294.554752 0.14031009 3.15970069 1.20655541 0.14031009096 0.5979856674.9968 1009.61652 288.459012 0.1468536 3.10828216 1.21556564 0.14685360162 0.6063842274.4968 994.309064 282.470237 0.15377422 3.05545325 1.22503033 0.15377442083 0.6147053373.9968 979.183867 276.586921 0.16111149 3.00112212 1.23499161 0.16111149158 0.6229609773.4968 964.239441 270.807571 0.16890935 2.94519943 1.24549509 0.16890934885 0.6311603372.9968 949.474299 265.130711 0.17722036 2.88757477 1.2565949 0.17722036286 0.6393173272.4968 934.886962 259.554877 0.18610611 2.82812433 1.26835339 0.18610610549 0.6474476271.9968 920.475953 254.078624 0.19563976 2.76670589 1.28084339 0.19563975924 0.6555698571.4968 906.239803 248.700519 0.20590933 2.70315326 1.29415098 0.20590933224 0.6637067570.9968 892.177046 243.419146 0.21702199 2.63727024 1.30837901 0.21702199006 0.6718863770.4968 878.286222 238.233101 0.22911001 2.56882252 1.32365186 0.22911009607 0.6801436469.9968 864.565876 233.140997 0.24234041 2.49752018 1.3401235 0.24234041288 0.6885244169.4968 851.014558 228.141461 0.25691248 2.42307722 1.35796879 0.25691948124 0.6970691368.9968 837.630825 223.233135 0.27315005 2.3448241 1.37748652 0.27315005042 0.7059120868.4968 824.413236 218.414674 0.29139314 2.26236354 1.3989528 0.29139313833 0.7151103867.9968 811.360358 213.684749 0.31219576 2.17478975 1.42283453 0.31219576318 0.7248438767.4968 798.470764 209.042044 0.33636154 2.08088796 1.44978172 0.33636154222 0.7353607766.9968 785.743029 204.485259 0.36517588 1.97875865 1.48080151 0.36517588417 0.7470709666.4968 773.175737 200.013107 0.4009275 1.86508982 1.51762688 0.40092750464 0.7607294465.9968 760.767475 195.624313 0.44849007 1.73296572 1.56381349 0.44849007304 0.77800278
65.9656634 760 195.353737 0.45206393 1.72381714 1.56715673 0.45206392657 0.7792755564.94 735.058317 186.616788 0.55 1.50796126 1.65208523 0.56 0.8021601464.32 720.297792 181.498297 0.6 1.41918439 1.69066762 0.63 0.8070279364.27 719.11771 181.09077 0.65 1.34173225 1.72621043 0.69 0.8252121464.16 716.526906 180.196952 0.7 1.27379524 1.75886477 0.74 0.8406526263.94 711.367427 178.420568 0.71 1.2612156 1.76506252 0.76 0.83816219
63.7 705.77244 176.499708 0.73 1.23697899 1.77713474 0.80 0.8385641463.54 702.061816 175.228934 0.8 1.16087711 1.8161219 0.89 0.8579026363.53 701.830415 175.14977 0.81 1.15100378 1.82129304 0.90 0.8609548263.57 702.756381 175.466609 0.82 1.14135785 1.82636818 0.84 0.82663.64 704.379144 176.022252 0.84 1.12272155 1.83623521 0.86 0.836863.87 709.731948 177.858489 0.86 1.10491736 1.84573244 0.90 0.86664.29 719.589559 181.253687 0.9 1.0716195 1.86365474 0.94 0.90765.07 720.297792 181.498297 0.6 1.41918439 1.69066762 0.98 0.962565.39 735.058317 186.616788 0.55 1.50796126 1.65208523 0.99 0.9805
65.9656634 760 195.353737 1 1.72381714 1.56715673 1 1
DIAGRAMA P-x,y a Temperatura constante
Ingrese la Temperatura en °C = 60
PsA= 623.833874 puro
PsB= 149.038419 puro
P Kpa PsA PsB xAsupuesto xA calculado yA149.038419 623.833874 149.038419 0 4.73338633 1 0 0179.038419 623.833874 149.038419 0.01021802 4.57891188 1.01583082 0.01021802445 0.16302414209.038419 623.833874 149.038419 0.02116538 4.42215811 1.03266766 0.02116538082 0.27932075239.038419 623.833874 149.038419 0.03294496 4.26290302 1.05063622 0.03294495665 0.36651829269.038419 623.833874 149.038419 0.04568258 4.10088339 1.06988737 0.04568258355 0.43439291299.038419 623.833874 149.038419 0.05953439 3.93578272 1.09060458 0.05953438992 0.48881105329.038419 623.833874 149.038419 0.07469715 3.76721707 1.11301382 0.07469733739 0.53351546359.038419 623.833874 149.038419 0.09142501 3.59469836 1.13740026 0.09142502163 0.57102551389.038419 623.833874 149.038419 0.11005138 3.41762086 1.16412736 0.11005138677 0.60310905419.038419 623.833874 149.038419 0.13102943 3.23518035 1.19367484 0.13102943911 0.63107714449.038419 623.833874 149.038419 0.15499652 3.04628424 1.22669499 0.15499615195 0.65596069479.038419 623.833874 149.038419 0.18288959 2.84939327 1.26411001 0.18288896222 0.67864082509.038419 623.833874 149.038419 0.21617617 2.64218298 1.30730237 0.21617615239 0.69998559539.038419 623.833874 149.038419 0.25737457 2.42078351 1.35852958 0.25737321304 0.72105902569.038419 623.833874 149.038419 0.31143135 2.17789311 1.42196821 0.31142030775 0.74357752599.038419 623.833874 149.038419 0.39066856 1.89634232 1.50724676 0.39066616853 0.7715063604.038419 623.833874 149.038419 0.40850338 1.84267349 1.52519634 0.40850333204 0.77740697609.038419 623.833874 149.038419 0.42859133 1.7858193 1.5448755 0.42859115016 0.78398032614.038419 623.833874 149.038419 0.45166654 1.72482939 1.56678585 0.45166655101 0.79147549619.038419 623.833874 149.038419 0.4789727 1.6580782 1.59176754 0.47897269528 0.80032636623.833874 623.833874 149.038419 0.51131272 1.58583428 1.62005372 0.51131271837 0.81085723624.833874 623.833874 149.038419 0.529739 1.5476564 1.63555193 0.52800751127 0.81854184625.833874 623.833874 149.038419 0.52961296 1.54791065 1.63544743 0.52928692788 0.8171737626.833874 623.833874 149.038419 0.531844 1.5434238 1.63729427 0.53255886535 0.81693209627.833874 623.833874 149.038419 0.540897 1.52551064 1.64472232 0.5416649104 0.81988705628.833874 623.833874 149.038419 0.55325 1.50180513 1.65468834 0.55373206147 0.82426723629.833874 623.833874 149.038419 0.563602 1.48256972 1.6628906 0.56421748535 0.82761926630.833874 623.833874 149.038419 0.57 1.47095859 1.66789242 0.57133500063 0.82914264631.833874 623.833874 149.038419 0.58 1.45322114 1.67560773 0.58173182916 0.83219624632.833874 623.833874 149.038419 0.59 1.43596878 1.68319907 0.59225633211 0.83517261633.833874 623.833874 149.038419 0.6 1.41918439 1.69066762 0.60290975699 0.83807634634.833874 623.833874 149.038419 0.61 1.40285157 1.69801457 0.61369334241 0.84091175635.833874 623.833874 149.038419 0.62 1.38695465 1.70524112 0.62460831698 0.84368289636.833874 623.833874 149.038419 0.63 1.37147862 1.71234847 0.63565589823 0.84639363637.833874 623.833874 149.038419 0.64 1.35640907 1.71933783 0.64683729153 0.84904759638.833874 623.833874 149.038419 0.65 1.34173225 1.72621043 0.65815368897 0.8516482639.833874 623.833874 149.038419 0.66 1.32743493 1.73296748 0.66960626829 0.85419869640.833874 623.833874 149.038419 0.69 1.28669604 1.75255762 0.70109909833 0.86426823641.833874 623.833874 149.038419 0.71 1.2612156 1.76506252 0.72322379618 0.87035014642.833874 623.833874 149.038419 0.74 1.22530262 1.78301168 0.75623807085 0.87992424643.833874 623.833874 149.038419 0.85 1.11371848 1.84102946 0.87882372757 0.89642.833874 623.833874 149.038419 0.83 1.13193259 1.8313485 0.91725371805 0.9641.833874 623.833874 149.038419 0.86 1.10491736 1.84573244 0.95 0.915640.833874 623.833874 149.038419 0.93 1.04850208 1.87619427 0.97 0.93
A B
639.833874 623.833874 149.038419 0.95 1.03390266 1.88414111 0.98585942866 0.95639.583874 623.833874 149.038419 0.95225 1.03229897 1.88501494 0.98788246474 0.95879977639.333874 623.833874 149.038419 0.95523 1.03018675 1.88616607 0.99078556124 0.96020763639.083874 623.833874 149.038419 0.95925 1.02735849 1.88770776 0.99494618006 0.9619775638.833874 623.833874 149.038419 0.9612 1.02599523 1.88845099 0.99660706054 0.96303067638.583874 623.833874 149.038419 0.96255 1.02505473 1.88896377 0.99754149586 0.96387642638.333874 623.833874 149.038419 0.96525 1.02318176 1.88998505 1.00010777866 0.96519188638.083874 623.833874 149.038419 0.97 1.01991252 1.89176789 1.00515903 0.96722128633.083874 623.833874 149.038419 0.971 1.01922842 1.89214098 0.99224102028 0.9752107632.833874 623.833874 149.038419 0.975 1.01650637 1.89362558 0.99631371407 0.97699863627.833874 623.833874 149.038419 0.99 1.00649953 1.89908317 0.9998415965 0.99008614623.833874 623.833874 149.038419 1 1 1.90262664 1 1
Raoult-DaltonxA yA
0 00.01065677 0.028257540.02137077 0.055931340.03214471 0.08303350.04298069 0.109574210.05388084 0.135563530.06484733 0.161011320.07588236 0.18592730.08698816 0.21032099
0.098167 0.234201770.1094212 0.257578870.1207531 0.28046136
0.13216508 0.302858130.14365957 0.324777960.15523904 0.34622946
0.166906 0.36722110.17866301 0.387761210.19051266 0.40785797
0.2024576 0.427519430.21450053 0.446753510.22664419 0.465567990.23889138 0.483970520.25124494 0.501968620.26370778 0.519569680.27628285 0.536780990.28897316 0.553609690.30178178 0.570062810.31471185 0.586147260.32776656 0.601869850.34094916 0.617237250.35426297 0.632256030.36771138 0.646932660.38129785 0.661273480.39502591 0.675284750.40889914 0.68897260.42292123 0.702343080.43709593 0.715402110.45142706 0.728155540.46591853 0.740609110.48057434 0.752768450.49539857 0.76463912
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 150
55
60
65
70
75
80
85
90
95
100
Composición x,y
Tem
pera
tura
(C°)
TeTetrahidrofurano vs. Agua Agua T (°C) vs X,Y
0.51039538 0.776226580.52556902 0.787536180.54092385 0.798573190.55646431 0.809342810.57219495 0.819850130.58812039 0.83010016
0.6042454 0.840097830.62057482 0.849847980.63711361 0.859355380.65386685 0.86862470.67083972 0.877660550.68803755 0.886467450.70546574 0.895049860.72312987 0.903412140.74103561 0.911558590.75918878 0.919493440.77759534 0.927220850.79626137 0.934744890.81519312 0.942069580.83439697 0.949198870.85387945 0.956136640.87364727 0.962886690.89370728 0.96945278
0.9140665 0.975838580.93473212 0.982047720.95571151 0.988083760.97701222 0.993950190.99864198 0.99965045
1 11.04547738 1.01116691.07368642 1.017597321.07598558 1.018105641.08105662 1.01921863
1.0912522 1.021422721.10245674 1.02379419
1.1099745 1.02535621.11044565 1.025453331.10856198 1.025064481.10527137 1.02438172
1.0945113 1.022117941.07506548 1.017902491.07368642 1.017597321.04547738 1.0111669
1 1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 150
55
60
65
70
75
80
85
90
95
100
Composición x,y
Tem
pera
tura
(C°)
TeTetrahidrofurano vs. Agua Agua T (°C) vs X,Y
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
x
yTetrahidrofurano vs. Agua
Y vs. X
Raoult-DaltonxA yA
0 00.0631851 0.22015949
0.12637021 0.377126920.18955531 0.494694640.25274041 0.586042810.31592552 0.659062610.37911062 0.718767270.44229573 0.768494510.50548083 0.81055250.56866593 0.846588420.63185104 0.877809250.69503614 0.905119650.75822124 0.929210990.82140635 0.950620740.88459145 0.969773030.94777655 0.98700701
0.9583074 0.989712910.96883826 0.992374380.97936911 0.99499250.98989996 0.99756833
1 11.00210617 1.000502371.00421234 1.001003141.00631851 1.001502311.00842468 1.001999891.01053085 1.002495891.01263702 1.002990311.01474319 1.003483171.01684936 1.003974471.01895553 1.00446421
1.0210617 1.004952411.02316787 1.005439071.02527404 1.005924191.02738021 1.00640781.02948638 1.006889891.03159255 1.007370471.03369872 1.007849541.03580489 1.008327131.03791106 1.008803221.04001723 1.00927783
1.0421234 1.009750971.04001723 1.009277831.03791106 1.008803221.03580489 1.00832713
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1140
165
190
215
240
265
290
315
340
365
390
415
440
465
490
515
540
565
590
615
640
665
P vs x,y a T cte
1.03369872 1.007849541.03317218 1.007729921.03264564 1.007610191.03211909 1.007490381.03159255 1.007370471.03106601 1.007250461.03053947 1.007130371.03001292 1.007010171.01948207 1.00458641.01895553 1.004464211.00842468 1.00199989
1 1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 150
55
60
65
70
75
80
85
90
95
100
Composición x,y
Tem
pera
tura
(C°)
TeTetrahidrofurano vs. Agua Agua T (°C) vs X,Y
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 150
55
60
65
70
75
80
85
90
95
100
Composición x,y
Tem
pera
tura
(C°)
TeTetrahidrofurano vs. Agua Agua T (°C) vs X,Y
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 10
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
x
y
Tetrahidrofurano vs. Agua Y vs. X
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1140
165
190
215
240
265
290
315
340
365
390
415
440
465
490
515
540
565
590
615
640
665
P vs x,y a T cte